ArticleOrganic letters2018
Total Synthesis of Chaetoglobin A via Catalytic, Atroposelective Oxidative Phenol Coupling.
Article in Organic letters, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Recent advances in oxidative phenol coupling for the total synthesis of natural products.Natural product reports · 2024Review
- Asymmetric Total Synthesis of Chaetoglobin A.The Journal of organic chemistry · 2023Article
- Deciphering the evolution of flavin-dependent monooxygenase stereoselectivity using ancestral sequence reconstruction.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Edge-Decorated Polycyclic Aromatic Hydrocarbons by an Oxidative Coupling Approach.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Catalytic Oxidative Coupling of Phenols and Related Compounds.ACS catalysis · 2022Article
- Cytochalasans and azaphilones: suitable chemotaxonomic markers for the Chaetomium species.Applied microbiology and biotechnology · 2021Review
- Total Synthesis of Pyrolaside B: Phenol Trimerization through Sequenced Oxidative C-C and C-O Coupling.Angewandte Chemie (International ed. in English) · 2020Article
- Diastereoselective Synthesis of Benzoxanthenones.Chemistry, an Asian journal · 2020Article
- Recent advances in the chemistry and biology of azaphilones.RSC advances · 2020Review
- Synthetic Applications of Oxidative Aromatic Coupling-From Biphenols to Nanographenes.Angewandte Chemie (International ed. in English) · 2020Review
- Stereodivergent, Chemoenzymatic Synthesis of Azaphilone Natural Products.Journal of the American Chemical Society · 2019Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
The first total synthesis of chaetoglobin A (1), which features a chiral axis between two identical highly oxygenated bicyclic cores, was successfully completed in 12 steps from 2,6-dimethoxytoluene. Vanadium-catalyzed oxidative phenol coupling, as a key step, enabled generation of the axial chirality.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.