ArticleDalton transactions (Cambridge, England : 2003)2018
Conformational twisting of a formate-bridged diiridium complex enables catalytic formic acid dehydrogenation.
Article in Dalton transactions (Cambridge, England : 2003), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
1 citing paper in PubMed.
- Pressurized Formic Acid Dehydrogenation: An Entropic Spring Replaces Hydrogen Compression Cost.Catalysis science & technology · 2022Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
We previously reported that iridium complex 1a enables the first homogeneous catalytic dehydrogenation of neat formic acid and enjoys unusual stability through millions of turnovers. Binuclear iridium hydride species 5a, which features a provocative C2-symmetric geometry, was isolated from the reaction as a catalyst resting state. By synthesizing and carefully examining the catalytic initiation of a series of analogues to 1a, we establish here a strong correlation between the formation of C2-twisted iridium dimers analogous to 5a and the reactivity of formic acid dehydrogenation: an efficient C2 twist appears unique to 1a and essential to catalytic reactivity.
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Registered trials
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