ArticleJournal of the American Chemical Society2018
Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 100 citations in OpenAlex.
- Recent Advances in Homogeneous Catalysis with Platinum Group Pincer Complexes: Hydrogen-Mediated Transformations and Cross-Coupling Reactions.Chemical record (New York, N.Y.) · 2026Review
- Si-H Activation via Dynamic Permutational Isomerism: A Ligand-Directed Route to Dehydrogenative Coupling.Angewandte Chemie (International ed. in English) · 2025Article
- Synthesis of bio-based N-containing compounds from biomass.National science review · 2025Review
- Facile synthesis of acridine-based nickel(II) complexes via metal-mediated rearrangement of diphenylamine derivative and application in HScientific reports · 2025Article
- Oxygen Vacancies in β-MoOResearch (Washington, D.C.) · 2025Article
- Green Synthesis of Aromatic Nitrogen-Containing Heterocycles by Catalytic and Non-Traditional Activation Methods.Molecules (Basel, Switzerland) · 2023Review
- Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia.Chemical science · 2022Article
- Sustainable catalysis with fluxional acridine-based PNP pincer complexes.Chemical communications (Cambridge, England) · 2022Review
- Acceptorless Dehydrogenation of Methanol to Carbon Monoxide and Hydrogen using Molecular Catalysts.Angewandte Chemie (International ed. in English) · 2021Article
- Synthesis of N-Heterocycles via Oxidant-Free Dehydrocyclization of Alcohols Using Heterogeneous Catalysts.Angewandte Chemie (International ed. in English) · 2021Review
- Hydrogen Transfer-Mediated Multicomponent Reaction for Direct Synthesis of Quinazolines by a Naphthyridine-Based Iridium Catalyst.iScience · 2020Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The synthesis of N-heteroaromatic compounds via an acceptorless dehydrogenative coupling process involving direct use of ammonia as the nitrogen source was explored. We report the synthesis of pyrazine derivatives from 1,2-diols and the synthesis of N-substituted pyrroles by a multicomponent dehydrogenative coupling of 1,4-diols and primary alcohols with ammonia. The acridine-based Ru-pincer complex 1 is an effective catalyst for these transformations, in which the acridine backbone is converted to an anionic dearomatized PNP-pincer ligand framework.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.