Evidence map›Paper›PMID 30185030›Full record

ArticleJournal of the American Chemical Society2018

Cation-π Interactions in the Benzylic Arylation of Toluenes with Bimetallic Catalysts.

Sheng-Chun Sha, Sergei Tcyrulnikov, Minyan Li, Bowen Hu, Yue Fu, Marisa C Kozlowski, Patrick J Walsh

Open access · greenAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.

0numbers the graph read from it
0cells of the map it votes in
18citing papers in PubMed
5.5field-weighted citation impact, top 3% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

18 citing papers in PubMed, 93 citations in OpenAlex.

  1. Deprotonation and Alkylation of Weakly Acidic C(spAngewandte Chemie (International ed. in English) · 2026
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  6. Cascade degradation and upcycling of polystyrene waste to high-value chemicals.Proceedings of the National Academy of Sciences of the United States of America · 2022
    Article
  7. Article
  8. Article
  9. Palladium-catalyzed benzylic C(spChemical science · 2021
    Article
  10. Article
  11. Asymmetric C(spCommunications chemistry · 2021
    Article
  12. Benzylic C(spChemical science · 2021
    Article
  13. Article
  14. Article
  15. Article
  16. Article
  17. Transition-metal-free C(spChemical science · 2020
    Article
  18. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 1 institution in 1 country.

Sheng-Chun ShaDepartment of Chemistry, Roy and Diana Vagelos Laboratories , University of Pennsylvania , Philadelphia , Pennsylvania 19104 , United States.
Sergei TcyrulnikovDepartment of Chemistry, Roy and Diana Vagelos Laboratories , University of Pennsylvania , Philadelphia , Pennsylvania 19104 , United States.
Minyan LiDepartment of Chemistry, Roy and Diana Vagelos Laboratories , University of Pennsylvania , Philadelphia , Pennsylvania 19104 , United States.ORCID 0000-0001-8120-6294
Bowen HuDepartment of Chemistry, Roy and Diana Vagelos Laboratories , University of Pennsylvania , Philadelphia , Pennsylvania 19104 , United States.
Yue FuDepartment of Chemistry, Roy and Diana Vagelos Laboratories , University of Pennsylvania , Philadelphia , Pennsylvania 19104 , United States.
Marisa C KozlowskiDepartment of Chemistry, Roy and Diana Vagelos Laboratories , University of Pennsylvania , Philadelphia , Pennsylvania 19104 , United States.ORCID 0000-0002-4225-7125
Patrick J WalshDepartment of Chemistry, Roy and Diana Vagelos Laboratories , University of Pennsylvania , Philadelphia , Pennsylvania 19104 , United States.ORCID 0000-0001-8392-4150
University of Pennsylvania · US

Funding

Computational Methods for Selective CatalysisR01GM087605 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI KOZLOWSKI, MARISA C · 2010 to 2019
$2.4M
NIGMS NIH HHS R01 GM087605
6 · The paper itself

Abstract

A method to directly arylate toluene derivatives with aryl bromides to generate diarylmethanes, which are important building blocks in drug discovery, is described. In this method, KN(SiMe

Indexed as

Biphenyl CompoundsCatalysisCationsPotassiumTolueneBiphenyl CompoundsCationsPotassiumToluene

Identifiers

PMID30185030
PMCPMC6200331
OpenAlexW2891603737

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.