ArticleChemical science2017
Porphyrinoid rotaxanes: building a mechanical picket fence.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- Strain-Controlled Synthesis of [Organic letters · 2025Article
- Multimodal Molecular Motion in the Rotaxanes and Catenanes Incorporating Flexible Calix[n]phyrin Stations.Angewandte Chemie (International ed. in English) · 2025Article
- Rotaxane-Functionalized Dyes for Charge-Rectification in p-Type Photoelectrochemical Devices.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Review
- Selective synthesis and structural transformation between a molecular ring-in-ring architecture and an abnormal trefoil knot.Chemical science · 2020Article
- Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 1-Azides, Porphyrins and Corroles.Molecules (Basel, Switzerland) · 2020Review
- Chemical Consequences of the Mechanical Bond: A Tandem Active Template-Rearrangement Reaction.Angewandte Chemie (International ed. in English) · 2019Article
- Effects of Center Metals in Porphines on Nanomechanical Gas Sensing.Sensors (Basel, Switzerland) · 2018Article
- Chelating Rotaxane Ligands as Fluorescent Sensors for Metal Ions.Angewandte Chemie (International ed. in English) · 2018Article
- Efficient Multicomponent Active Template Synthesis of Catenanes.Journal of the American Chemical Society · 2018Article
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Building on recent progress in the synthesis of functional porphyrins for a range of applications using the Cu-mediated azide-alkyne cycloaddition (CuAAC) reaction, we describe the active template CuAAC synthesis of interlocked triazole functionalised porphyrinoids in excellent yield. By synthesising interlocked analogues of previously studied porphyrin-corrole conjugates, we demonstrate that this approach gives access to rotaxanes in which the detailed electronic properties of the axle component are unchanged but whose steric properties are transformed by the mechanical "picket fence" provided by the threaded rings. Our results suggest that interlocked functionalised porphyrins, readily available using the AT-CuAAC approach, are sterically hindered scaffolds for the development of new catalysts and materials.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.