ArticleChemical Society reviews2018
Radicals in natural product synthesis.
Article in Chemical Society reviews, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 67 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
67 citing papers in PubMed.
- Competing pathways in electrocarboxylation on copper electrodes: defining reactivity regimes through substrate activation and COFaraday discussions · 2026Article
- Densely-functionalized bicyclic cyclopentanones by combined photoinduced 6-Organic chemistry frontiers : an international journal of organic chemistry · 2026Article
- Harnessing redox properties of organic persistent radicals in SET-induced transformations.Beilstein journal of organic chemistry · 2026Review
- Unveiling mechanistic patterns of copper-catalyzed radical bond formation through linear free energy relationship.Nature communications · 2025Article
- Electrochemical dechlorination and hydrocarbon valorization by cobalt phthalocyanine with non-proton-coupled redox property.Nature communications · 2025Article
- On-Surface Synthesis of Nonbenzenoid PAHs Using Intermolecular π-Radical C-C Coupling.Journal of the American Chemical Society · 2025Article
- Cobalt-catalyzed reductive cross-coupling: a review.Molecular diversity · 2025Review
- Synthesis of the Spirotetracyclic Core of the Ginkgolides via a Malonyl Radical Cascade.Organic letters · 2025Article
- Factors Controlling Diastereoselectivity and Reactivity in the Catalytic Aerobic Carbooxygenation of (E)-2-Fluoro-3-aryl-allyl Nitroacetates.Chemistry, an Asian journal · 2025Article
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- Light-promoted borylation and lactonization of propargyl acetates using NHC-borane.RSC advances · 2025Article
- A Dual Catalytic Approach for the Halogen-Bonding-Mediated Reductive Cleavage of α-Bromodifluoroesters and Amides.The Journal of organic chemistry · 2025Article
- Asymmetric total synthesis of tricyclic prostaglandin D2 metabolite methyl ester via oxidative radical cyclization.Beilstein journal of organic chemistry · 2025Article
- Electrochemical Deconstructive Methoxylation of Arylalcohols-A Synthetic and Mechanistic Investigation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Electrochemical Synthesis of C(spOrganic letters · 2024Article
- A Spin-Labeled Derivative of Gossypol.Molecules (Basel, Switzerland) · 2024Article
- Non-Aufbau electronic structure in radical enzymes and control of the highly reactive intermediates.Chemical science · 2024Article
- Photocatalytic Enantioselective Radical Cascade Multicomponent Minisci Reaction of β-Carbolines Using Diazo Compounds as Radical Precursors.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- A Mechanistic Investigation of theThe Journal of organic chemistry · 2024Article
- Advancements in visible-light-induced reactions via alkenyl radical intermediates.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2024Review
7 more citing papers are in PubMed but not listed here.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
Abstract
Free radical intermediates have intrigued chemists since their discovery, and an ever-increasing appreciation for their unique reactivity has resulted in the widespread utilization of these species throughout the field of chemical synthesis. This is most evident from the recent surge in the application of intermolecular radical reactions that feature in complex molecule syntheses. This tutorial review will discuss the diverse methods utilized for radical generation and reactivity to form critical bonds in natural product total synthesis. In particular, stabilized (e.g. benzyl) and persistent (e.g. TEMPO) radicals will be the primary focus.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.