Evidence map›Paper›PMID 30091829›Full record

ArticleAngewandte Chemie (International ed. in English)2018

Enantioselective Construction of Tertiary Boronic Esters by Conjunctive Cross-Coupling.

Jesse A Myhill, Liang Zhang, Gabriel J Lovinger, James P Morken

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers.

0numbers the graph read from it
0cells of the map it votes in
29citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

29 citing papers in PubMed.

  1. Article
  2. Nickel-Catalyzed Boron-Mediated Saturative Trifunctionalization of Alkynes.Angewandte Chemie (International ed. in English) · 2026
    Article
  3. Review
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Article
  12. Article
  13. Stereospecific 1,2-Migrations of Boronate Complexes Induced by Electrophiles.Angewandte Chemie (International ed. in English) · 2020
    Review
  14. Article
  15. Article
  16. Radical-Induced 1,2-Migrations of Boron Ate Complexes.Advanced synthesis & catalysis · 2020
    Review
  17. Article
  18. Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Acyclic Olefins.Angewandte Chemie (International ed. in English) · 2020
    Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Jesse A MyhillDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA, 02467, USA.
Liang ZhangDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA, 02467, USA.
Gabriel J LovingerDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA, 02467, USA.
James P MorkenDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA, 02467, USA.ORCID 0000-0002-9123-9791

Funding

New Strategies in Catalytic Organic Synthesis with Organoboron ReagentsR35GM127140 · NIGMS · BOSTON COLLEGE · PI JAMES Patrick MORKEN · 2018 to 2026
$5.1M
NIGMS NIH HHS R35-GM1217140NIGMS NIH HHS R35 GM127140
6 · The paper itself

Abstract

Catalytic enantioselective conjunctive cross-coupling has been developed to construct tertiary alkylboronic esters. These reactions occur with good yield and enantioselectivity for a range of substrates. Mechanistic experiments reveal aspects of the catalytic cycle that allow hindered substrates to react without significant complicating side reactions.

Indexed as

BoronCatalysisCoordination ComplexesEstersKineticsPalladiumStereoisomerismThermodynamicsBoronCoordination ComplexesEstersPalladiumasymmetric catalysisboroncross couplingquaternary centers

Identifiers

PMID30091829
PMCPMC6414220

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.