Evidence map›Paper›PMID 30077145›Full record

ArticleJournal of magnetic resonance (San Diego, Calif. : 1997)2018

Electron decoupling with cross polarization and dynamic nuclear polarization below 6 K.

Erika L Sesti, Edward P Saliba, Nicholas Alaniva, Alexander B Barnes

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of magnetic resonance (San Diego, Calif. : 1997), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Homonuclear J-couplings and heteronuclear structural constraints.Journal of magnetic resonance (San Diego, Calif. : 1997) · 2024
    Article
  2. Electron-decoupled MAS DNP with N@CPhysical chemistry chemical physics : PCCP · 2023
    Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Erika L SestiDepartment of Chemistry, Washington University in St. Louis, One Brookings Drive, St. Louis, MO 63130, USA.
Edward P SalibaDepartment of Chemistry, Washington University in St. Louis, One Brookings Drive, St. Louis, MO 63130, USA.
Nicholas AlanivaDepartment of Chemistry, Washington University in St. Louis, One Brookings Drive, St. Louis, MO 63130, USA.
Alexander B BarnesDepartment of Chemistry, Washington University in St. Louis, One Brookings Drive, St. Louis, MO 63130, USA. Electronic address: barnesab@wustl.edu.

Funding

HIGH-SENSITIVITY NMR AT ROOM TEMPERATURE FOR MOLECULAR STRUCTURE AND DYNAMICSDP2GM119131 · NIGMS · WASHINGTON UNIVERSITY · PI BARNES, ALEXANDER BENJAMIN · 2015 to 2018
$2.7M
NIGMS NIH HHS DP2 GM119131
6 · The paper itself

Abstract

Dynamic nuclear polarization (DNP) can improve nuclear magnetic resonance (NMR) sensitivity by orders of magnitude. Polarizing agents containing unpaired electrons required for DNP can broaden nuclear resonances in the presence of appreciable hyperfine couplings. Here we present the first cross polarization experiments implemented with electron decoupling, which attenuates detrimental hyperfine couplings. We also demonstrate magic angle spinning (MAS) DNP experiments below 6 K, producing unprecedented nuclear spin polarization in rotating solids.

Indexed as

AlgorithmsCarbon IsotopesDiffusionElectronsMagnetic Resonance SpectroscopySignal-To-Noise RatioTritiumUreaCarbon IsotopesTritiumUrea2-D NMRCryogenic magic angle spinningDynamic nuclear polarizationElectron decoupling

Identifiers

PMID30077145
PMCPMC7015119

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.