ReviewAngewandte Chemie (International ed. in English)2019
Molecular Engineering of Free-Base Porphyrins as Ligands-The N-H⋅⋅⋅X Binding Motif in Tetrapyrroles.
Review in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed.
- Co-loading Radio-photosensitizer Agents on Polymer and Lipid-based Nanocarriers for Radio-photodynamic Therapy Purposes: Review.Current pharmaceutical design · 2026Review
- Healable Dielectric Elastomer Actuator With Premature Breakdown Warning Function for Information Transmission Encryption and Human-Machine Interaction.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Advances in the use of metal-free tetrapyrrolic macrocycles as catalysts.Beilstein journal of organic chemistry · 2024Review
- Free-Base Corrole Anion.The Journal of organic chemistry · 2023Article
- Self-Organization of Porphyrin-POM Dyads: Nonplanar Diacids and Oxoanions in Low-Dimensional H-Bonding Networks.Molecules (Basel, Switzerland) · 2022Article
- Nanoformulation of Tetrapyrroles Derivatives in Photodynamic Therapy: A Focus on Bacteriochlorin.Evidence-based complementary and alternative medicine : eCAM · 2022Review
- Solid-Contact Ion-Selective Electrodes for Histamine Determination.Sensors (Basel, Switzerland) · 2021Article
- Strategic Synthesis of 'Picket Fence' Porphyrins Based on Nonplanar Macrocycles.European journal of organic chemistry · 2021Article
- Nucleophilic Aromatic Substitution (SEuropean journal of organic chemistry · 2021Review
- Elucidating Atropisomerism in Nonplanar Porphyrins with Tunable Supramolecular Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Structural effects of meso-halogenation on porphyrins.Beilstein journal of organic chemistry · 2021Article
- Preparations of Core HACS omega · 2020Article
- Weak Interactions and Conformational Changes in Core-Protonated AMolecules (Basel, Switzerland) · 2020Article
- Porphyrins as Colorimetric and Photometric Biosensors in Modern Bioanalytical Systems.Chembiochem : a European journal of chemical biology · 2020Review
- Short-Chained Anthracene Strapped Porphyrins and their Endoperoxides.European journal of organic chemistry · 2020Article
- Facile Supramolecular Engineering of Porphyrin cis Tautomers: The Case of β-Octabromo-ACS omega · 2020Article
- Crystal structures of 2,3,7,8,12,13,17,18-octa-bromo-5,10,15,20-tetra-kis-(penta-fluoro-phen-yl)porphyrin as the chloro-form monosolvate and tetra-hydro-furan monosolvate.Acta crystallographica. Section E, Crystallographic communications · 2020Article
- Conformational Re-engineering of Porphyrins as Receptors with Switchable N-H⋅⋅⋅X-Type Binding Modes.Angewandte Chemie (International ed. in English) · 2019Article
- Synthesis and characterization of rigid [2.2]paracyclophane-porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes.RSC advances · 2019Article
- The role of π-π stacking and hydrogen-bonding interactions in the assembly of a series of isostructural group IIB coordination compounds.Acta crystallographica. Section C, Structural chemistry · 2019Article
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2 authors.
Funding
Abstract
The core N-H units of planar porphyrins are often inaccessible to forming hydrogen-bonding complexes with acceptor molecules. This is due to the fact that the amine moieties are "shielded" by the macrocyclic system, impeding the formation of intermolecular H-bonds. However, methods exist to modulate the tetrapyrrole conformations and to reshape the vector of N-H orientation outwards, thus increasing their availability and reactivity. Strategies include the use of porpho(di)methenes and phlorins (calixphyrins), as well as saddle-distorted porphyrins. The former form cavities due to interruption of the aromatic system. The latter are highly basic systems and capable of binding anions and neutral molecules via N-H⋅⋅⋅X-type H-bonds. This Review discusses the role of porphyrin(oid) ligands in various coordination-type complexes, means to access the core for hydrogen bonding, the concept of conformational control, and emerging applications, such as organocatalysis and sensors.
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