Evidence map›Paper›PMID 30061612›Full record

ArticleNature chemistry2018

Broadband 2D IR spectroscopy reveals dominant asymmetric H

Joseph A Fournier, William B Carpenter, Nicholas H C Lewis, Andrei Tokmakoff

Abstract read
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In one paragraph

Article in Nature chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.

0numbers the graph read from it
0cells of the map it votes in
31citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

31 citing papers in PubMed.

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  12. Rotational dive into the water clusters on a simple sugar substrate.Proceedings of the National Academy of Sciences of the United States of America · 2023
    Article
  13. The birth and evolution of solvated electrons in the water.Proceedings of the National Academy of Sciences of the United States of America · 2023
    Article
  14. Article
  15. Article
  16. Ultrafast Continuum IR Generation and Its Application in IR Spectroscopy.International journal of molecular sciences · 2022
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Joseph A FournierDepartment of Chemistry, James Franck Institute, and Institute for Biophysical Dynamics, The University of Chicago, Chicago, IL, USA.ORCID http://orcid.org/0000-0001-7569-9176
William B CarpenterDepartment of Chemistry, James Franck Institute, and Institute for Biophysical Dynamics, The University of Chicago, Chicago, IL, USA.ORCID http://orcid.org/0000-0002-6174-1035
Nicholas H C LewisDepartment of Chemistry, James Franck Institute, and Institute for Biophysical Dynamics, The University of Chicago, Chicago, IL, USA.ORCID http://orcid.org/0000-0002-2554-0199
Andrei TokmakoffDepartment of Chemistry, James Franck Institute, and Institute for Biophysical Dynamics, The University of Chicago, Chicago, IL, USA. tokmakoff@uchicago.edu.ORCID http://orcid.org/0000-0002-2434-8744

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Given the critical role of the aqueous excess proton in redox chemistry, determining its structure and the mechanism of its transport in water are intense areas of experimental and theoretical research. The ultrafast dynamics of the proton's hydration structure has made it extremely challenging to study experimentally. Using ultrafast broadband two-dimensional infrared spectroscopy, we show that the vibrational spectrum of the aqueous proton is fully consistent with a protonated water complex broadly defined as a Zundel-like H

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.