ArticleNature communications2018
Exploring the performance of nanostructured reagents with organic-group-defined morphology in cross-coupling reaction.
Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
9 citing papers in PubMed, 38 citations in OpenAlex.
- Synthesis, Properties, and Electrochemical Proton Reduction of a Homoleptic Tetrathiolato Ni-Site Model of [NiFe]-Hydrogenase.Inorganic chemistry · 2025Article
- Highly active reduced graphene oxide supported Ni nanoparticles for C-S coupling reactions.Nanoscale advances · 2022Article
- Article
- Deep neural network analysis of nanoparticle ordering to identify defects in layered carbon materials.Chemical science · 2021Article
- Ionic liquids: prospects for nucleic acid handling and delivery.Nucleic acids research · 2021Review
- Sterically Hindered Phosphonium Salts: Structure, Properties and Palladium Nanoparticle Stabilization.Nanomaterials (Basel, Switzerland) · 2020Article
- Selectivity control in thiol-yne click reactionsChemical science · 2020Article
- Electron microscopy dataset for the recognition of nanoscale ordering effects and location of nanoparticles.Scientific data · 2020Article
- Organic-Inorganic Hybrid Nanomaterials.Nanomaterials (Basel, Switzerland) · 2019Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
The great impact of the nanoscale organization of reactive species on their performance in chemical transformations creates the possibility of fine-tuning of reaction parameters by modulating the nano-level properties. This methodology is extensively applied for the catalysts development whereas nanostructured reactants represent the practically unexplored area. Here we report the palladium- and copper-catalyzed cross-coupling reaction involving nano-structured nickel thiolate particles as reagents. On the basis of experimental findings we propose the cooperative effect of nano-level and molecular-level properties on their reactivity. The high degree of ordering, small particles size, and electron donating properties of the substituents favor the product formation. Reactant particles evolution in the reaction is visualized directly by dynamic liquid-phase electron microscopy including recording of video movies. Mechanism of the reaction in liquid phase is established using on-line mass spectrometry measurements. Together the findings provide new opportunities for organic chemical transformations design and for mechanistic studies.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.