Evidence map›Paper›PMID 30034749›Full record

ArticleChemical science2016

Highly luminescent palladium(ii) complexes with sub-millisecond blue to green phosphorescent excited states. Photocatalysis and highly efficient PSF-OLEDs.

Pui-Keong Chow, Gang Cheng, Glenna So Ming Tong, Chensheng Ma, Wai-Ming Kwok, Wai-Hung Ang, Clive Yik-Sham Chung, Chen Yang, Feng Wang, Chi-Ming Che

Abstract read
In one paragraph

Article in Chemical science, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.

0numbers the graph read from it
0cells of the map it votes in
20citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

20 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Chemical science · 2025
    Article
  5. Article
  6. Article
  7. Phosphorescent PdAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024
    Article
  8. Article
  9. Dual-Lifetime Referencing (Sensors (Basel, Switzerland) · 2023
    Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Article
  16. Article
  17. Article
  18. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Pui-Keong ChowState Key Laboratory of Synthetic Chemistry , Institute of Molecular Functional Materials , HKU-CAS Joint Laboratory on New Materials and Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China . Email: cmche@hku.hk.
Gang ChengState Key Laboratory of Synthetic Chemistry , Institute of Molecular Functional Materials , HKU-CAS Joint Laboratory on New Materials and Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China . Email: cmche@hku.hk.
Glenna So Ming TongState Key Laboratory of Synthetic Chemistry , Institute of Molecular Functional Materials , HKU-CAS Joint Laboratory on New Materials and Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China . Email: cmche@hku.hk.
Chensheng MaSchool of Chemistry and Chemical Engineering , Shenzhen University , Shenzhen 518060 , China.
Wai-Ming KwokDepartment of Applied Biology and Chemical Technology , The Hong Kong Polytechnic University , Hung Hom , Kowloon , Hong Kong SAR , China.
Wai-Hung AngState Key Laboratory of Synthetic Chemistry , Institute of Molecular Functional Materials , HKU-CAS Joint Laboratory on New Materials and Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China . Email: cmche@hku.hk.
Clive Yik-Sham ChungState Key Laboratory of Synthetic Chemistry , Institute of Molecular Functional Materials , HKU-CAS Joint Laboratory on New Materials and Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China . Email: cmche@hku.hk.
Chen YangState Key Laboratory of Synthetic Chemistry , Institute of Molecular Functional Materials , HKU-CAS Joint Laboratory on New Materials and Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China . Email: cmche@hku.hk.
Feng WangState Key Laboratory of Synthetic Chemistry , Institute of Molecular Functional Materials , HKU-CAS Joint Laboratory on New Materials and Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China . Email: cmche@hku.hk.
Chi-Ming CheState Key Laboratory of Synthetic Chemistry , Institute of Molecular Functional Materials , HKU-CAS Joint Laboratory on New Materials and Department of Chemistry , The University of Hong Kong , Pokfulam Road , Hong Kong , China . Email: cmche@hku.hk.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Palladium(ii) complexes supported by tetradentate [N^C^C^N] and [O^N^C^N] ligand systems display sky blue to red phosphorescence with emission quantum yields and emission lifetimes up to 0.64 and 272 μs, respectively. Femtosecond time-resolved fluorescence (fs-TRF) measurements on these Pd(ii) complexes reveal a fast intersystem crossing from singlet to triplet manifolds with time constants of 0.6-21 ps. DFT/TDDFT calculations revealed that, as a result of the spiro-fluorene and bridging tertiary amine units of the ligands, the T

Identifiers

PMID30034749
PMCPMC6024183

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