ArticleChemical science2016
Facile hydrogen atom transfer to iron(iii) imido radical complexes supported by a dianionic pentadentate ligand.
Article in Chemical science, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Selective Chiral Diamine-bisoxazoline Iron(II) Catalysts for Pyrrolidine Formation via Intramolecular C(spJournal of the American Chemical Society · 2025Article
- Iron(III)-Mediated C-H Alkylation: One-Electron Differentiation Increases Activity and Chemoselectivity.Journal of the American Chemical Society · 2025Article
- Oxidation-induced ambiphilicity triggers N-N bond formation and dinitrogen release in octahedral terminal molybdenum(v) nitrido complexes.Chemical science · 2024Article
- Spin polarization assisted facile C-H activation by anChemical science · 2023Article
- A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N-O Reagent as the "Amino" Source and "Oxidant".Journal of the American Chemical Society · 2022Article
- Investigation of iron-ammine and amido complexes within a CDalton transactions (Cambridge, England : 2003) · 2021Article
- A Terminal Imido Complex of an Iron-Sulfur Cluster.Angewandte Chemie (International ed. in English) · 2021Article
- Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate.Chemical science · 2020Article
- NHNature chemistry · 2020Article
- Synthesis of Chromium(II) Complexes with Chelating Bis(alkoxide) Ligand and Their Reactions with Organoazides and Diazoalkanes.Molecules (Basel, Switzerland) · 2020Article
- Synthesis, characterization and C-H amination reactivity of nickel iminyl complexes.Chemical science · 2019Article
- Octahedral iron(iv)-tosylimido complexes exhibiting single electron-oxidation reactivity.Chemical science · 2019Article
- A Two-Coordinate Iron(II) Imido Complex with NHC Ligation: Synthesis, Characterization, and Its Diversified Reactivity of Nitrene Transfer and C-H Bond Activation.Inorganic chemistry · 2019Article
- Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer.Angewandte Chemie (International ed. in English) · 2019Article
- Direct Comparison of C-H Bond Amination Efficacy through Manipulation of Nitrogen-Valence Centered Redox: Imido versus Iminyl.Journal of the American Chemical Society · 2017Article
- Nitrene Radical Intermediates in Catalytic Synthesis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2017Article
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A dianionic tetrapodal pentadentate diborate ligand is introduced. This ligand forms a high spin neutral iron(ii) complex that reacts with a variety of organoazides to yield transient Fe(iii) imido radicals that are extremely potent hydrogen atom abstractors. The nature of these species is supported by full characterization of the Fe(iii) amido products, kinetic studies, density functional computations and Mössbauer spectroscopy on the -C
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