Evidence map›Paper›PMID 30032611›Full record

ArticleJournal of the American Chemical Society2018

Experimental and Computational Study of the ( Z)-Selective Formation of Trisubstituted Olefins and Benzo-Fused Oxacycles from the Ruthenium-Catalyzed Dehydrative C-H Coupling of Phenols with Ketones.

Hanbin Lee, Manoj V Mane, Ho Ryu, Debashis Sahu, Mu-Hyun Baik, Chae S Yi

Open access · greenAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
1.6field-weighted citation impact, top 18% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 29 citations in OpenAlex.

  1. Cooperative Lewis Acid/Metal Dual Catalysis for the SelectiveACS sustainable chemistry & engineering · 2025
    Article
  2. CspChemical science · 2024
    Review
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 3 institutions in 2 countries.

Hanbin LeeDepartment of Chemistry , Marquette University , Milwaukee , Wisconsin 53201-1881 , United States.
Manoj V ManeCenter for Catalytic Hydrocarbon Functionalizations , Institute for Basic Science (IBS) , Daejeon 34141 , Republic of Korea.
Ho RyuCenter for Catalytic Hydrocarbon Functionalizations , Institute for Basic Science (IBS) , Daejeon 34141 , Republic of Korea.ORCID 0000-0001-8450-991X
Debashis SahuCenter for Catalytic Hydrocarbon Functionalizations , Institute for Basic Science (IBS) , Daejeon 34141 , Republic of Korea.
Mu-Hyun BaikCenter for Catalytic Hydrocarbon Functionalizations , Institute for Basic Science (IBS) , Daejeon 34141 , Republic of Korea.ORCID 0000-0002-8832-8187
Chae S YiDepartment of Chemistry , Marquette University , Milwaukee , Wisconsin 53201-1881 , United States.ORCID 0000-0002-4504-1151
Institute for Basic Science · KRKorea Advanced Institute of Science and Technology · KRMarquette University · US

Funding

Catalytic Coupling Reactions via C-H and C-N Bond ActivationR15GM109273 · NIGMS · MARQUETTE UNIVERSITY · PI YI, CHAE S · 2014 to 2014
$334k
NIGMS NIH HHS R15 GM109273
6 · The paper itself

Abstract

The cationic Ru-H complex was found to be an effective catalyst for the dehydrative C-H coupling of phenols with ketones to form the trisubstituted olefin products. The coupling of phenol with linear ketones led to highly stereoselective formation of the ( Z)-olefin products. The dehydrative coupling of phenol with enones and diones efficiently formed the benzopyrene and related oxacyclic derivatives. The reaction of 3,5-dimethoxyphenol with cyclohexanone-2,2,6,6- d

Indexed as

AlkenesCatalysisComputer SimulationKetonesModels, MolecularMolecular StructurePhenolsRutheniumAlkenesKetonesPhenolsRuthenium

Identifiers

PMID30032611
PMCPMC6558961
OpenAlexW2883140155

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.