ArticleAngewandte Chemie (International ed. in English)2018
Palladium/Rhodium Cooperative Catalysis for the Production of Aryl Aldehydes and Their Deuterated Analogues Using the Water-Gas Shift Reaction.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Chemical kinetics and promoted Co-immobilization for efficient catalytic carbonylation of ethylene oxide into methyl 3-hydroxypropionate.Frontiers in chemistry · 2022Article
- Copper-catalysed low-temperature water-gas shift reaction for selective deuteration of aryl halides.Chemical science · 2021Article
- Selective oxidation of alcohol-RSC advances · 2021Article
- Deuteration of Formyl Groups via a Catalytic Radical H/D Exchange Approach.ACS catalysis · 2020Article
- Formyl-selective deuteration of aldehydes with DChemical science · 2019Article
- Practical Synthesis of C-1 Deuterated Aldehydes Enabled by NHC Catalysis.Nature catalysis · 2019Article
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Abstract
A novel Pd/Rh dual-metallic cooperative catalytic process has been developed to effect the reductive carbonylation of aryl halides in moderate to good yield. In this reaction, water is the hydride source, and CO serves both as the carbonyl source and the terminal reductant through the water-gas shift reaction. The catalytic generation of the Rh hydride allows for the selective formation of highly hindered aryl aldehydes that are inaccessible through previously reported reductive carbonylation protocols. Moreover, aldehydes with deuterated formyl groups can be efficiently and selectively synthesized using D
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