ArticleChemical science2018
An N-heterocyclic carbene ligand promotes highly selective alkyne semihydrogenation with copper nanoparticles supported on passivated silica.
Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
13 citing papers in PubMed.
- Metal-Nanomaterials (Basel, Switzerland) · 2026Article
- NMR Spectroscopic Signatures of Cationic Surface Sites from Supported Coinage Metals Interacting with N-Heterocyclic Carbenes.Journal of the American Chemical Society · 2024Article
- Enhanced catalytic activity of N-heterocyclic carbene stabilized surface adatoms for CO reduction reaction.Communications chemistry · 2023Article
- On-surface synthesis of ballbot-type N-heterocyclic carbene polymers.Nature chemistry · 2023Article
- NHC stabilized copper nanoparticlesChemical communications (Cambridge, England) · 2023Article
- Stereoselective Semi-Hydrogenations of Alkynes by First-Row (3d) Transition Metal Catalysts.ChemCatChem · 2022Review
- N-Heterocyclic Carbene Modified Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide.Journal of the American Chemical Society · 2022Article
- Growth of N-Heterocyclic Carbene Assemblies on Cu(100) and Cu(111): From Single Molecules to Magic-Number Islands.Angewandte Chemie (International ed. in English) · 2022Article
- Article
- Controlled growth of ultrafine metal nanoparticles mediated by solid supports.Nanoscale advances · 2021Review
- Multichannel gas-uptake/evolution reactor for monitoring liquid-phase chemical reactions.The Review of scientific instruments · 2021Article
- New poly-imidazolium-triazole particles by CuAAC cross-linking of calix[4]arene bis-azide/alkyne amphiphiles - a prospective support for Pd in the Mizoroki-Heck reaction.RSC advances · 2020Article
- Nickel-Catalyzed Stereodivergent Synthesis of E- and Z-Alkenes by Hydrogenation of Alkynes.ChemSusChem · 2019Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report a surface organometallic route that generates copper nanoparticles (NPs) on a silica support while simultaneously passivating the silica surface with trimethylsiloxy groups. The material is active for the catalytic semihydrogenation of phenylalkyl-, dialkyl- and diaryl-alkynes and displays high chemo- and stereoselectivity at full alkyne conversion to corresponding (
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.