ArticleChemical science2016
Competition-driven selection in covalent dynamic networks and implementation in organic reactional selectivity.
Article in Chemical science, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- Photosulfoxidation Catalysis as the Driving Principle for Deazaoxaflavin Photoredox Catalyst Formation.The Journal of organic chemistry · 2025Article
- Aromatic-Carbonyl Interactions as an Emerging Type of Non-Covalent Interactions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Constitutional adaptation to pChemical science · 2024Article
- Multiple control of azoquinoline based molecular photoswitches.Chemical science · 2024Article
- Triple Self-Sorting in Constitutional Dynamic Networks: Parallel Generation of Imine-Based CuAngewandte Chemie (International ed. in English) · 2020Article
- n → π* interactions as a versatile tool for controlling dynamic imine chemistry in both organic and aqueous media.Chemical science · 2020Article
- Self-sorting of two imine-based metal complexes: balancing kinetics and thermodynamics in constitutional dynamic networks.Chemical science · 2019Article
- Environmental control programs the emergence of distinct functional ensembles from unconstrained chemical reactions.Proceedings of the National Academy of Sciences of the United States of America · 2019Article
- Antiparallel Dynamic Covalent Chemistries.Journal of the American Chemical Society · 2017Article
- Coevolution and ratiometric behaviour in metal cation-driven dynamic covalent systems.Chemical science · 2017Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Competition among reagents in dynamic combinatorial libraries of increased complexity leads to reactional self-sorting (improved regioselectivity) in mixtures of aldehydes and oligoamines. High selectivity of a given library component is transferred to a different reacting component of low selectivity through a network of underlying equilibrating reactions which provide component exchange between all species. The selectivity of various carbonyl compounds in reactions with amines was also assessed towards the formation of defined sequences of residues along oligoamine chains. The approach was further exploited for defining selective dynamic protecting groups (DPGs), based on the reversible linkage between the substrate and the protecting group. They represent an intermediate approach between the conventional protecting groups and the protecting-group-free approach in organic synthesis. Removal of the protecting group is effected
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.