ArticleChemical science2016
High yielding synthesis of 2,2'-bipyridine macrocycles, versatile intermediates in the synthesis of rotaxanes.
Article in Chemical science, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 35 papers.
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Who cites it
35 citing papers in PubMed.
- Nickel-catalysed synthesis of symmetrical and unsymmetrical 2,2'-bipyridinesRSC advances · 2026Article
- Modulation of Lanthanide Luminescence with the Mechanical Bond: Antenna-Emitter Confinement in a Compact [2]Rotaxane.Angewandte Chemie (International ed. in English) · 2025Article
- Organic Cage Rotaxanes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Strain-Controlled Synthesis of [Organic letters · 2025Article
- Synthesis of a Station-Less Molecular Daisy Chain.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Multimodal Molecular Motion in the Rotaxanes and Catenanes Incorporating Flexible Calix[n]phyrin Stations.Angewandte Chemie (International ed. in English) · 2025Article
- The End of the Beginning of Mechanical Stereochemistry.Accounts of chemical research · 2024Article
- The Final Stereogenic Unit of [2]Rotaxanes: Type 2 Geometric Isomers.Journal of the American Chemical Society · 2024Article
- Dynamic mechanostereochemical switching of a co-conformationally flexible [2]catenane controlled by specific ionic guests.Nature communications · 2024Article
- Direct Detection of Hydrogen Bonds in Supramolecular Systems UsingJournal of the American Chemical Society · 2022Article
- Synthesis and Chemosensory Properties of New Cyanosubstituted 2,2'-Bipyridine Derivatives.Journal of fluorescence · 2022Article
- Mechanically axially chiral catenanes and noncanonical mechanically axially chiral rotaxanes.Nature chemistry · 2022Article
- A Co-conformationally "Topologically" Chiral Catenane.Journal of the American Chemical Society · 2022Article
- Highly selective synthesis and near-infrared photothermal conversion of metalla-Borromean ring and [2]catenane assemblies.Chemical science · 2022Article
- Anion-π Catalysis Enabled by the Mechanical Bond.Angewandte Chemie (International ed. in English) · 2022Article
- Can 2-Pyridyl-1,2,3-triazole "Click" Ligands be Used to Develop Cu(I)/Cu(II) Molecular Switches?ACS omega · 2021Article
- Rotaxane CoAngewandte Chemie (International ed. in English) · 2021Article
- Damming an electronic energy reservoir: ion-regulated electronic energy shuttling in a [2]rotaxane.Chemical science · 2021Article
- Using the Mechanical Bond to Tune the Performance of a Thermally Activated Delayed Fluorescence Emitter*.Angewandte Chemie (International ed. in English) · 2021Article
- Spin-labelled mechanically interlocked molecules as models for the interpretation of biradical EPR spectra.Chemical science · 2021Article
Corrections and comments
- Erratum issued
Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We present an operationally simple approach to 2,2'-bipyridine macrocycles. Our method uses simple starting materials to produce these previously hard to access rotaxane precursors in remarkable yields (typically >65%) across a range of scales (0.1-5 mmol). All of the macrocycles reported are efficiently converted (>90%) to rotaxanes under AT-CuAAC conditions. With the requisite macrocycles finally available in sufficient quantities, we further demonstrate their long term utility through the first gram-scale synthesis of an AT-CuAAC [2]rotaxane and extend this powerful methodology to produce novel Sauvage-type molecular shuttles.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.