ArticleAngewandte Chemie (International ed. in English)2018
Enantioconvergent Biocatalytic Redox Isomerization.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Review
- Fully Biocatalytic Rearrangement of Furans to Spirolactones.ACS catalysis · 2023Article
- Peroxidase-induced C-N bond formationGreen chemistry : an international journal and green chemistry resource : GC · 2023Article
- Aerobic C-N Bond Formation through Enzymatic Nitroso-Ene-Type Reactions.Angewandte Chemie (International ed. in English) · 2023Article
- Ru-Catalyzed Isomerization of Achmatowicz Derivatives: A Sustainable Route to Biorenewables and Bioactive Lactones.ACS catalysis · 2023Article
- Coding Synthetic Chemistry Strategies for Furan Valorization into Bacterial Designer Cells.ChemSusChem · 2023Article
- Cascade Catalysis Through Bifunctional Lipase Metal Biohybrids for the Synthesis of Enantioenriched O-Heterocycles from Allenes.ChemCatChem · 2022Article
- Enantioconvergent Biocatalytic Redox Isomerization.Angewandte Chemie (International ed. in English) · 2018Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Alcohol dehydrogenases can act as powerful catalysts in the preparation of optically pure γ-hydroxy-δ-lactones by means of an enantioconvergent dynamic redox isomerization of readily available Achmatowicz-type pyranones. Imitating the traditionally metal-mediated "borrowing hydrogen" approach to shuffle hydrides across molecular architectures and interconvert functional groups, this chemoinspired and purely biocatalytic interpretation effectively expands the enzymatic toolbox and provides new opportunities in the assembly of multienzyme cascades and tailor-made cellular factories.
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Registered trials
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