ArticleScience advances2018
Stretching vibration is a spectator in nucleophilic substitution.
Article in Science advances, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
12 citing papers in PubMed.
- Controlling the Stereodynamics of the FACS physical chemistry Au · 2026Article
- Vibrational Spectroscopy Through Time Averaged Fourier Transform of Autocorrelated Molecular Dynamics Data: Introducing the Free SEMISOFT Web-Platform.Journal of computational chemistry · 2025Article
- A dynamic isotope effect in the nucleophilic substitution reaction between FNature communications · 2025Article
- Reaction dynamics of the methoxy anion CHFaraday discussions · 2024Article
- Imaging the Atomistic Dynamics of Single Proton Transfer and Combined Hydrogen/Proton Transfer in the OThe journal of physical chemistry. A · 2022Article
- Dynamically Hidden Reaction Paths in the Reaction of CFACS physical chemistry Au · 2022Article
- Fifty years of nucleophilic substitution in the gas phase.Mass spectrometry reviews · 2021Review
- First-Principles Reaction Dynamics beyond Six-Atom Systems.The journal of physical chemistry. A · 2021Article
- Rotational Mode Specificity in the FThe journal of physical chemistry. A · 2020Article
- Quantitative Dynamics of the NACS omega · 2020Article
- Influence of Vibrational Excitation on the Reaction of FThe journal of physical chemistry letters · 2020Article
- Too slow to be activated.Nature chemistry · 2019Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
How chemical reactions are influenced by reactant vibrational excitation is a long-standing question at the core of chemical reaction dynamics. In reactions of polyatomic molecules, where the Polanyi rules are not directly applicable, certain vibrational modes can act as spectators. In nucleophilic substitution reactions, CH stretching vibrations have been considered to be such spectators. While this picture has been challenged by some theoretical studies, experimental insight has been lacking. We show that the nucleophilic substitution reaction of F
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.