ArticleChemistry (Weinheim an der Bergstrasse, Germany)2018
Photodissociation of Sodium Iodide Clusters Doped with Small Hydrocarbons.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
11 citing papers in PubMed.
- Salt Cluster With Surface Defect Shows Anomalous Acid-Base Chemistry.Angewandte Chemie (International ed. in English) · 2026Article
- Magic cluster sizes of cationic and anionic sodium chloride clusters explained by statistical modeling of the complete phase space.Physical chemistry chemical physics : PCCP · 2024Article
- Spectroscopy of cluster aerosol models: IR and UV spectra of hydrated glyoxylate with and without sea salt.Environmental science: atmospheres · 2023Article
- [MoAngewandte Chemie (International ed. in English) · 2021Article
- UV/Vis Spectroscopy of Copper Formate Clusters: Insight into Metal-Ligand Photochemistry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Evidence for lactone formation during infrared multiple photon dissociation spectroscopy of bromoalkanoate doped salt clusters.Physical chemistry chemical physics : PCCP · 2020Article
- Infrared Multiple Photon Dissociation Spectroscopy of Hydrated Cobalt Anions Doped with Carbon Dioxide CoCOChemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Decomposition of Copper Formate Clusters: Insight into Elementary Steps of Calcination and Carbon Dioxide Activation.ChemistryOpen · 2019Article
- Infrared Spectroscopy of Size-Selected Hydrated Carbon Dioxide Radical Anions COChemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
- Infrared multiple photon dissociation of cesium iodide clusters doped with mono-, di- and triglycine.European journal of mass spectrometry (Chichester, England) · 2019Article
- Photodissociation of Sodium Iodide Clusters Doped with Small Hydrocarbons.Chemistry (Weinheim an der Bergstrasse, Germany) · 2018Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors.
Funding
Abstract
Marine aerosols consist of a variety of compounds and play an important role in many atmospheric processes. In the present study, sodium iodide clusters with their simple isotope pattern serve as model systems for laboratory studies to investigate the role of iodide in the photochemical processing of sea-salt aerosols. Salt clusters doped with camphor, formate and pyruvate are studied in a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) coupled to a tunable laser system in both UV and IR range. The analysis is supported by ab initio calculations of absorption spectra and energetics of dissociative channels. We provide quantitative analysis of IRMPD measurements by reconstructing one-photon spectra and comparing them with the calculated ones. While neutral camphor is adsorbed on the cluster surface, the formate and pyruvate ions replace an iodide ion. The photodissociation spectra revealed several wavelength-specific fragmentation pathways, including the carbon dioxide radical anion formed by photolysis of pyruvate. Camphor and pyruvate doped clusters absorb in the spectral region above 290 nm, which is relevant for tropospheric photochemistry, leading to internal conversion followed by intramolecular vibrational redistribution, which leads to decomposition of the cluster. Potential photodissociation products of pyruvate in the actinic region may be formed with a cross section of <2×10
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.