Evidence map›Paper›PMID 29977377›Full record

ArticleBeilstein journal of organic chemistry2018

Hypervalent iodine-guided electrophilic substitution:

Cyrus Mowdawalla, Faiz Ahmed, Tian Li, Kiet Pham, Loma Dave, Grace Kim, I F Dempsey Hyatt

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Beilstein journal of organic chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Exploring benzylicChemical science · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Cyrus MowdawallaDepartment of Chemistry and Biochemistry, Adelphi University, 1 South Ave., Garden City, NY, 11530, USA.ORCID 0000-0002-3908-1771
Faiz AhmedDepartment of Chemistry and Biochemistry, Adelphi University, 1 South Ave., Garden City, NY, 11530, USA.ORCID 0000-0002-3280-843X
Tian LiDepartment of Chemistry and Biochemistry, Adelphi University, 1 South Ave., Garden City, NY, 11530, USA.
Kiet PhamDepartment of Chemistry and Biochemistry, Adelphi University, 1 South Ave., Garden City, NY, 11530, USA.
Loma DaveDepartment of Chemistry and Biochemistry, Adelphi University, 1 South Ave., Garden City, NY, 11530, USA.
Grace KimDepartment of Chemistry and Biochemistry, Adelphi University, 1 South Ave., Garden City, NY, 11530, USA.ORCID 0000-0002-6044-483X
I F Dempsey HyattDepartment of Chemistry and Biochemistry, Adelphi University, 1 South Ave., Garden City, NY, 11530, USA.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The reactivity of benzyl hypervalent iodine intermediates was explored in congruence with the reductive iodonio-Claisen rearrangement (RICR) to show that there may be an underlying mechanism which expands the reasoning behind the previously known C-C bond-forming reaction. By rationalizing the hypervalent iodine's metal-like properties it was concluded that a transmetallation mechanism could be occurring with metalloid groups such as silicon and boron. Hypervalent iodine reagents such as Zefirov's reagent, cyclic iodonium reagents, iodosobenzene/BF

Indexed as

electrophilic aromatic substitutionhypernucleofugalityhypervalent iodineiodonio-Claisentransmetallation

Identifiers

PMID29977377
PMCPMC6009249

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.