ArticleAngewandte Chemie (International ed. in English)2018
Regiospecific N-Arylation of Aliphatic Amines under Mild and Metal-Free Reaction Conditions.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents.Chemical reviews · 2024Review
- Recent Advances in Synthetic Routes to Azacycles.Molecules (Basel, Switzerland) · 2023Review
- Recent Progress in Cyclic Aryliodonium Chemistry: Syntheses and Applications.Chemical reviews · 2023Review
- Copper-catalyzedBeilstein journal of organic chemistry · 2023Article
- Recent Advances in Transition-Metal-Free Late-Stage C-H and N-H Arylation of Heteroarenes Using Diaryliodonium Salts.Pharmaceuticals (Basel, Switzerland) · 2021Review
- Transition Metal-Free N-Arylation of Amino Acid Esters with Diaryliodonium Salts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Article
- Cu-catalyzedOrganic letters · 2020Article
- Concerted Nucleophilic Aromatic Substitution Reactions.Angewandte Chemie (International ed. in English) · 2019Review
- Copper-catalyzed synthesis of phenol and diaryl ether derivativesRSC advances · 2019Article
- Regiospecific N-Arylation of Aliphatic Amines under Mild and Metal-Free Reaction Conditions.Angewandte Chemie (International ed. in English) · 2018Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A transition metal-free N-arylation of primary and secondary amines with diaryliodonium salts is presented. Both acyclic and cyclic amines are well tolerated, providing a large set of N-alkyl anilines. The methodology is unprecedented among metal-free methods in terms of amine scope, the ability to transfer both electron-withdrawing and electron-donating aryl groups, and efficient use of resources, as excess substrate or reagents are not required.
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