ArticleNature communications2018
Thermally-induced reversible structural isomerization in colloidal semiconductor CdS magic-size clusters.
Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Spectroscopic Evidence in Optical Absorption for the Formation and Transformation of Prenucleation Clusters of CdS Quantum Dots.ACS central science · 2026Article
- Resonant and non-resonant driving of linearly-polarized excitons in CdNature communications · 2026Article
- Carboxylic acid isomer-directed synthesis of CdS nanocluster isomers.Chemical science · 2024Article
- Dynamic Metal Nanoclusters: A Review on Accurate Crystal Structures.Molecules (Basel, Switzerland) · 2023Review
- Direct and Indirect Pathways of CdTeSe Magic-Size Cluster Isomerization Induced by Surface Ligands at Room Temperature.ACS central science · 2023Article
- Stable CsPbBrJournal of the American Chemical Society · 2022Article
- Review
- Silver Nanoparticle-Based Sensor for the Selective Detection of Nickel Ions.Nanomaterials (Basel, Switzerland) · 2021Article
- Evolution of Photoluminescent CdS Magic-Size Clusters Assisted by Adding Small Molecules with Carboxylic Group.ACS omega · 2021Article
- Highly luminescent and catalytically active suprastructures of magic-sized semiconductor nanoclusters.Nature materials · 2021Article
- Interplay between Perovskite Magic-Sized Clusters and Amino Lead Halide Molecular Clusters.Research (Washington, D.C.) · 2021Article
- Atomically precise nanoclusters with reversible isomeric transformation for rotary nanomotors.Nature communications · 2020Article
- Room-temperature formation of CdS magic-size clusters in aqueous solutions assisted by primary amines.Nature communications · 2020Article
- First Synthesis of Mn-Doped Cesium Lead Bromide Perovskite Magic Sized Clusters at Room Temperature.The journal of physical chemistry letters · 2020Article
- Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole.Molecules (Basel, Switzerland) · 2019Article
- Carboxylic acid stimulated silver shell isomerism in a triple core-shell AgChemical science · 2019Article
- Formation of colloidal alloy semiconductor CdTeSe magic-size clusters at room temperature.Nature communications · 2019Article
- Precursor Self-Assembly Identified as a General Pathway for Colloidal Semiconductor Magic-Size Clusters.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2018Article
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Authors and funding
13 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Structural isomerism of colloidal semiconductor nanocrystals has been largely unexplored. Here, we report one pair of structural isomers identified for colloidal nanocrystals which exhibit thermally-induced reversible transformations behaving like molecular isomerization. The two isomers are CdS magic-size clusters with sharp absorption peaks at 311 and 322 nm. They have identical cluster masses, but slightly different structures. Furthermore, their interconversions follow first-order unimolecular reaction kinetics. We anticipate that such isomeric kinetics are applicable to a variety of small-size functional nanomaterials, and that the methodology developed for our kinetic study will be helpful to investigate and exploit solid-solid transformations in other semiconductor nanocrystals. The findings on structural isomerism should stimulate attention toward advanced design and synthesis of functional nanomaterials enabled by structural transformations.
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