Evidence map›Paper›PMID 29941915›Full record

ArticleNature communications2018

Direct observation of exciton-exciton interactions.

Jakub Dostál, Franziska Fennel, Federico Koch, Stefanie Herbst, Frank Würthner, Tobias Brixner

Abstract read
In one paragraph

Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.

0numbers the graph read from it
0cells of the map it votes in
17citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

17 citing papers in PubMed.

  1. Article
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  9. Article
  10. Dynamics of the energy transfer involved in a diarylethene-perylenebisimide dyad: comparison between the molecule and the nanoparticle level.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2023
    Article
  11. Article
  12. Article
  13. Design and Control of Perylene Supramolecular Polymers through Imide Substitutions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Review
  14. Article
  15. Article
  16. Article
  17. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Jakub DostálInstitut für Physikalische und Theoretische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Franziska FennelInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.ORCID http://orcid.org/0000-0003-2266-1179
Federico KochInstitut für Physikalische und Theoretische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Stefanie HerbstInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Frank WürthnerInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany. wuerthner@uni-wuerzburg.de.ORCID http://orcid.org/0000-0001-7245-0471
Tobias BrixnerInstitut für Physikalische und Theoretische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany. brixner@phys-chemie.uni-wuerzburg.de.ORCID http://orcid.org/0000-0002-6529-704X

Funding

Deutsche Forschungsgemeinschaft (German Research Foundation) FOR 1809EC | European Research Council (ERC) MULTISCOPE
6 · The paper itself

Abstract

Natural light harvesting as well as optoelectronic and photovoltaic devices depend on efficient transport of energy following photoexcitation. Using common spectroscopic methods, however, it is challenging to discriminate one-exciton dynamics from multi-exciton interactions that arise when more than one excitation is present in the system. Here we introduce a coherent two-dimensional spectroscopic method that provides a signal only in case that the presence of one exciton influences the behavior of another one. Exemplarily, we monitor exciton diffusion by annihilation in a perylene bisimide-based J-aggregate. We determine quantitatively the exciton diffusion constant from exciton-exciton-interaction 2D spectra and reconstruct the annihilation-free dynamics for large pump powers. The latter enables for ultrafast spectroscopy at much higher intensities than conventionally possible and thus improves signal-to-noise ratios for multichromophore systems; the former recovers spatio-temporal dynamics for a broad range of phenomena in which exciton interactions are present.

Identifiers

PMID29941915
PMCPMC6018121

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.