ArticleJournal of the American Chemical Society2018
Redox-Neutral Photocatalytic Cyclopropanation via Radical/Polar Crossover.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 57 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
57 citing papers in PubMed.
- Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Direct photoexcitation of borate complexes for radical generation: A platform from organic synthesis to chemical biology.Proceedings of the Japan Academy. Series B, Physical and biological sciences · 2026Review
- Unlocking nucleophilic reactivity in Co-MHAT catalysis: Stereospecific backside-backside displacement by anion-activated organocobalt.Science advances · 2025Article
- Overcoming Challenges in Small-Ring Transfer: Direct Decarboxylative Hydroalkylation of Alkenes via Iron-Thiol Catalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Redox-neutral photocatalytic cleavage andScience advances · 2025Article
- Methyl Radical Addition Reactions to C═X Double Bonds.The Journal of organic chemistry · 2025Article
- Electron donor-acceptor complex-driven photocatalyst-free synthesis of nitrocyclopropanes.RSC advances · 2025Article
- A Photocatalytic Approach to Radical 1-(Trifluoromethyl)cyclopropanation.ACS catalysis · 2025Article
- Synthesis of α-substituted cyclic boronatesChemical science · 2025Article
- Photocatalytic Strategy for Decyanative Transformations Enabled by Amine-Ligated Boryl Radical.Organic letters · 2025Article
- Enhancing Electron Donor-Acceptor Complex Photoactivation with a Stable Perylene Diimide Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Organophotocatalyst Enabled Deoxycyclopropanation of Alcohols.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Alkene Carboxy-Alkylation via COJournal of the American Chemical Society · 2024Article
- Organoelectrocatalytic cyclopropanation of alkenyl trifluoroborates with methylene compounds.Nature communications · 2024Article
- Discovery of BAY-405: An Azaindole-Based MAP4K1 Inhibitor for the Enhancement of T-Cell Immunity against Cancer.Journal of medicinal chemistry · 2024Article
- Radical Polarity.Journal of the American Chemical Society · 2024Article
- Reductive Cyclopropanation through Bismuth Photocatalysis.Journal of the American Chemical Society · 2024Article
- Red-light-mediated copper-catalyzed photoredox catalysis promotes regioselectivity switch in the difunctionalization of alkenes.Nature communications · 2024Article
- Electroreductive Radical Addition-Polar Cyclization Cascade to Access Cycloalkanes.Organic letters · 2024Article
- Iron(III)-based metalloradical catalysis for asymmetric cyclopropanation via a stepwise radical mechanism.Nature chemistry · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
Abstract
A benchtop stable, bifunctional reagent for the redox-neutral cyclopropanation of olefins has been developed. Triethylammonium bis(catecholato)iodomethylsilicate can be readily prepared on multigram scale. Using this reagent in combination with an organic photocatalyst and visible light, cyclopropanation of an array of olefins, including trifluoromethyl- and pinacolatoboryl-substituted alkenes, can be accomplished in a matter of hours. The reaction is highly tolerant of traditionally reactive functional groups (carboxylic acids, basic heterocycles, alkyl halides, etc.) and permits the chemoselective cyclopropanation of polyolefinated compounds. Mechanistic interrogation revealed that the reaction proceeds via a rapid anionic 3- exo- tet ring closure, a pathway consistent with experimental and computational data.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.