Evidence map›Paper›PMID 29910970›Full record

ArticleACS catalysis2017

Oxidation of Hindered Allylic C-H Bonds with Applications to the Functionalization of Complex Molecules.

Zachary C Litman, Ankit Sharma, John F Hartwig

Open access · greenAbstract read
In one paragraph

Article in ACS catalysis, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
1.5field-weighted citation impact, top 20% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 23 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors at 1 institution in 1 country.

Zachary C LitmanDepartment of Chemistry, University of California, Berkeley, California 94720, United States.
Ankit SharmaDepartment of Chemistry, University of California, Berkeley, California 94720, United States.
John F HartwigDepartment of Chemistry, University of California, Berkeley, California 94720, United States.
University of California, Berkeley · US

Funding

Mechanism and Development of Catalysts for the Synthesis of Amines, Ethers, and SR37GM055382 · NIGMS · UNIVERSITY OF ILLINOIS AT URBANA-CHAMPAIGN · PI HARTWIG, JOHN F · 2009 to 2018
$4.4M
TRANSITION METAL-CATALYZED SYNTHESIS OF AMINES AND ETHERR01GM055382 · NIGMS · YALE UNIVERSITY · PI HARTWIG, JOHN F · 2001 to 2008
$2.5M
PALLADIUM CATALYZED FORMATION OF ARYLAMINE AND ARYLETHERR29GM055382 · NIGMS · YALE UNIVERSITY · PI HARTWIG, JOHN F · 1997 to 2000
$185k
NIGMS NIH HHS R01 GM055382NIGMS NIH HHS R29 GM055382NIGMS NIH HHS R37 GM055382
6 · The paper itself

Abstract

We report the palladium-catalyzed oxidation of hindered alkenes to form linear allylic esters. The combination of palladium(II) benzoate, 4,5-diazafluoren-9-one, and benzoquinone catalyzes the mild oxidation of terminal alkenes with

Indexed as

allylic oxidationC–H activationC–H bond functionalizationolefin functionalizationpalladium catalysis

Identifiers

PMID29910970
PMCPMC5999342
OpenAlexW2582355309

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.