ArticleNature communications2018
Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling.
Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
4 citing papers in PubMed.
- Converting COCommunications chemistry · 2023Article
- AlNature communications · 2022Article
- Electron transport properties of PAlNanoscale advances · 2021Article
- Tuning the electronic properties of hexanuclear cobalt sulfide superatomsChemical science · 2019Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Alkali atoms have unusually low ionization energies because their electronic structures have an excess electron beyond that of a filled electronic shell. Quantum states in metallic clusters are grouped into shells similar to those in atoms, and clusters with an excess electron beyond a closed electronic may also exhibit alkali character. This approach based on shell-filling is the way alkali species are formed as explained by the periodic table. We demonstrate that the ionization energy of metallic clusters with both filled and unfilled electronic shells can be substantially lowered by attaching ligands. The ligands form charge transfer complexes where the electronic spectrum is lifted via crystal field like effect. We demonstrate that the effect works for the weakly bound ligand, N-ethyl-2-pyrrolidone (EP = C
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Registered trials
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