Evidence map›Paper›PMID 29899959›Full record

ArticleChemical science2018

Recyclable heterogeneous metal foil-catalyzed cyclopropenation of alkynes and diazoacetates under solvent-free mechanochemical reaction conditions.

Longrui Chen, Devonna Leslie, Michael G Coleman, James Mack

Abstract read
In one paragraph

Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Review
  5. Article
  6. Article
  7. Catalytic Synthesis of Cyclopropenium Cations with Rh-Carbynoids.Journal of the American Chemical Society · 2022
    Article
  8. The Direct Mechanocatalytic Suzuki-Miyaura Reaction of Small Organic Molecules.Angewandte Chemie (International ed. in English) · 2022
    Article
  9. Review
  10. Article
  11. Review
  12. Direct Mechanocatalysis: Using Milling Balls as Catalysts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020
    Review
  13. Article
  14. Article
  15. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Longrui ChenDepartment of Chemistry , University of Cincinnati , Cincinnati , Ohio 45221-0037 , USA . Email: james.mack@uc.edu.
Devonna LeslieSchool of Chemistry and Materials Science , Rochester Institute of Technology , Rochester , New York 14623-5604 , USA . Email: mgcsch@rit.edu.
Michael G ColemanSchool of Chemistry and Materials Science , Rochester Institute of Technology , Rochester , New York 14623-5604 , USA . Email: mgcsch@rit.edu.
James MackDepartment of Chemistry , University of Cincinnati , Cincinnati , Ohio 45221-0037 , USA . Email: james.mack@uc.edu.ORCID 0000-0001-5717-8916

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Silver and copper foil were found to be effective, versatile and selective heterogeneous catalysts for the cyclopropenation of terminal and internal alkynes under mechanochemical reaction conditions. This methodology enables the functionalization of a wide range of terminal or internal alkynes under ambient, aerobic, and solvent-free conditions. Finally, we have demonstrated a unique and versatile one-pot domino Sonogashira-cyclopropenation mechanochemical reaction for the formation of complex cyclopropenes.

Identifiers

PMID29899959
PMCPMC5969500

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.