ArticleOrganic letters2018
Direct Synthesis of Chiral Porphyrin Macrocyclic Receptors via Regioselective Nitration.
Article in Organic letters, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed.
- Kinetic enantio-recognition of chiral viologen guests by planar-chiral porphyrin cages.Chemical communications (Cambridge, England) · 2023Article
- Host-Guest Exchange of Viologen Guests in Porphyrin Cage Compounds as Studied by Selective Exchange Spectroscopy (1D EXSY) NMR.Angewandte Chemie (International ed. in English) · 2021Article
- Enantioselective synthesis of chiral porphyrin macrocyclic hosts and kinetic enantiorecognition of viologen guests.Chemical science · 2021Article
- Double Porphyrin Cage Compounds.European journal of organic chemistry · 2020Article
- Molecular motor-functionalized porphyrin macrocycles.Nature communications · 2020Article
- Absolute configuration and host-guest binding of chiral porphyrin-cages by a combined chiroptical and theoretical approach.Nature communications · 2020Article
- Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles.European journal of organic chemistry · 2019Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Nitration of tetraphenylporphyrin cage compound 1, at -40 °C, leads to the regioselective formation of the chiral mononitro compound 2 (75% isolated yield) and, at -30 °C, to the achiral syn-dinitro-derivative 3 and the chiral anti-dinitro derivative 4 in a diastereomeric ratio of 5:2, which were separated by chromatography (46 and 20% yields, respectively). The structures of the compounds were confirmed by X-ray crystallography.
Identifiers
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Registered trials
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