ArticleProceedings of the National Academy of Sciences of the United States of America2018
Monitoring molecular nonadiabatic dynamics with femtosecond X-ray diffraction.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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17 citing papers in PubMed.
- Transient-Absorption Pump-Probe Spectra as Information-Rich Observables: Case Study of Fulvene.Molecules (Basel, Switzerland) · 2025Article
- Pushing the limits of ultrafast diffraction: Imaging quantum coherences in isolated molecules.iScience · 2024Review
- Attosecond electron microscopy and diffraction.Science advances · 2024Article
- Raman Spectroscopy of Conical Intersections Using Entangled Photons.The journal of physical chemistry letters · 2024Article
- Monitoring vibronic coherences and molecular aromaticity in photoexcited cyclooctatetraene with an X-ray probe: a simulation study.Chemical science · 2023Article
- Time-resolved X-ray and XUV based spectroscopic methods for nonadiabatic processes in photochemistry.Chemical communications (Cambridge, England) · 2022Review
- Electronic coherences in nonadiabatic molecular photophysics revealed by time-resolved photoelectron spectroscopy.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Time-Resolved Photoelectron Spectroscopy of Conical Intersections with Attosecond Pulse Trains.The journal of physical chemistry letters · 2021Article
- Unveiling the spatial distribution of molecular coherences at conical intersections by covariance X-ray diffraction signals.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Capturing fingerprints of conical intersection: Complementary information of non-adiabatic dynamics from linear x-ray probes.Structural dynamics (Melville, N.Y.) · 2021Article
- Imaging conical intersection dynamics during azobenzene photoisomerization by ultrafast X-ray diffraction.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Signatures of electronic and nuclear coherences in ultrafast molecular x-ray and electron diffraction.Structural dynamics (Melville, N.Y.) · 2021Article
- Born-Oppenheimer approximation in optical cavities: from success to breakdown.Chemical science · 2020Article
- Ultrafast Spectroscopy of Photoactive Molecular Systems from First Principles: Where We Stand Today and Where We Are Going.Journal of the American Chemical Society · 2020Article
- Imaging electron-density fluctuations by multidimensional X-ray photon-coincidence diffraction.Proceedings of the National Academy of Sciences of the United States of America · 2019Article
- Multiscale wavelet decomposition of time-resolved X-ray diffraction signals in cyclohexadiene.Proceedings of the National Academy of Sciences of the United States of America · 2018Article
- QnAs with Shaul Mukamel.Proceedings of the National Academy of Sciences of the United States of America · 2018Article
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4 authors.
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Abstract
Ultrafast time-resolved X-ray scattering, made possible by free-electron laser sources, provides a wealth of information about electronic and nuclear dynamical processes in molecules. The technique provides stroboscopic snapshots of the time-dependent electronic charge density traditionally used in structure determination and reflects the interplay of elastic and inelastic processes, nonadiabatic dynamics, and electronic populations and coherences. The various contributions to ultrafast off-resonant diffraction from populations and coherences of molecules in crystals, in the gas phase, or from single molecules are surveyed for core-resonant and off-resonant diffraction. Single-molecule [Formula: see text] scaling and two-molecule [Formula: see text] scaling contributions, where N is the number of active molecules, are compared. Simulations are presented for the excited-state nonadiabatic dynamics of the electron harpooning at the avoided crossing in NaF. We show how a class of multiple diffraction signals from a single molecule can reveal charge-density fluctuations through multidimensional correlation functions of the charge density.
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