ArticleThe journal of physical chemistry letters2018
2D Chemistry: Chemical Control of Graphene Derivatization.
Article in The journal of physical chemistry letters, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
13 citing papers in PubMed.
- Fluorine-Incorporated Graphene Oxide for Hydrovoltaic Power Generation: Improving Proton Migration and Storage Capacity.ChemSusChem · 2026Article
- Electronic Structure of Metalloporphenes, Antiaromatic Analogues of Graphene.Journal of the American Chemical Society · 2024Article
- Metal-free cysteamine-functionalized graphene alleviates mutual interferences in heavy metal electrochemical detection.Green chemistry : an international journal and green chemistry resource : GC · 2023Article
- Manifesting Epoxide and Hydroxyl Groups in XPS Spectra and Valence Band of Graphene Derivatives.Nanomaterials (Basel, Switzerland) · 2022Article
- Emerging graphene derivatives as active 2D coordination platforms for single-atom catalysts.Nanoscale · 2022Review
- Edge Effect in Electronic and Transport Properties of 1D Fluorinated Graphene Materials.Nanomaterials (Basel, Switzerland) · 2021Article
- Graphene with Covalently Grafted Amino Acid as a Route Toward Eco-Friendly and Sustainable Supercapacitors.ChemSusChem · 2021Article
- Enhancing and Tuning the Nonlinear Optical Response and Wavelength-Agile Strong Optical Limiting Action ofNanomaterials (Basel, Switzerland) · 2020Article
- Room-Temperature Transport Properties of Graphene with Defects Derived from Oxo-Graphene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Graphene oxide-iridium nanocatalyst for the transformation of benzylic alcohols into carbonyl compounds.RSC advances · 2020Article
- Combined high degree of carboxylation and electronic conduction in graphene acid sets new limits for metal free catalysis in alcohol oxidation.Chemical science · 2019Article
- Chemical Tuning of Specific Capacitance in Functionalized Fluorographene.Chemistry of materials : a publication of the American Chemical Society · 2019Article
- Alkynylation of graphene via the Sonogashira C-C cross-coupling reaction on fluorographene.Chemical communications (Cambridge, England) · 2019Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Controllable synthesis of graphene derivatives with defined composition and properties represents the holy grail of graphene chemistry, especially in view of the low reactivity of graphene. Recent progress in fluorographene (FG) chemistry has opened up new routes for synthesizing a plethora of graphene derivatives with widely applicable properties, but they are often difficult to control. We explored nucleophilic substitution on FG combining density functional theory calculations with experiments to achieve accurate control over the functionalization process. In-depth analysis revealed the complexity of the reaction and identified basic rules for controlling the 2D chemistry. Their application, that is, choice of solvent and reaction time, enabled facile control over the reaction of FG with N-octylamine to form graphene derivatives with tailored content of the alkylamine functional group (2.5-7.5% N atomic content) and F atoms (31.5-3.5% F atomic content). This work substantially extends prospects for the controlled covalent functionalization of graphene.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.