ArticleChemistry of materials : a publication of the American Chemical Society2018
Polymer-Based Black Phosphorus (bP) Hybrid Materials by in Situ Radical Polymerization: An Effective Tool To Exfoliate bP and Stabilize bP Nanoflakes.
Article in Chemistry of materials : a publication of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
10 citing papers in PubMed, 65 citations in OpenAlex.
- Nanoscale Evaluation of the Degradation Stability of Black Phosphorus Nanosheets Functionalized with PEG and Glutathione-Stabilized Doxorubicin Drug-Loaded Gold Nanoparticles in Real Functionalized System.Molecules (Basel, Switzerland) · 2024Article
- Dispersion of Few-Layer Black Phosphorus in Binary Polymer Blend and Block Copolymer Matrices.Nanomaterials (Basel, Switzerland) · 2021Article
- Interlayer Coordination of Pd-Pd Units in Exfoliated Black Phosphorus.Journal of the American Chemical Society · 2021Article
- Phase-Changing Microcapsules Incorporated with Black Phosphorus for Efficient Solar Energy Storage.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2020Article
- Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals.ChemCatChem · 2020Article
- Advanced Black Phosphorus Nanomaterials for Bone Regeneration.International journal of nanomedicine · 2020Review
- Recent Advances in Chemical Functionalization of 2D Black Phosphorous Nanosheets.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2020Review
- Noncovalent Functionalization of 2D Black Phosphorus with Fluorescent Boronic Derivatives of Pyrene for Probing and Modulating the Interaction with Molecular Oxygen.ACS applied materials & interfaces · 2019Article
- A Perspective on Recent Advances in Phosphorene Functionalization and Its Applications in Devices.European journal of inorganic chemistry · 2019Review
- Modelling strategies for the covalent functionalization of 2D phosphorene.Dalton transactions (Cambridge, England : 2003) · 2018Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
13 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Black phosphorus (bP) has been recently investigated for next generation nanoelectronic multifunctional devices. However, the intrinsic instability of exfoliated bP (the bP nanoflakes) toward both moisture and air has so far overshadowed its practical implementation. In order to contribute to fill this gap, we report here the preparation of new hybrid polymer-based materials where bP nanoflakes (bPn) exhibit a significantly improved stability. The new materials have been prepared by different synthetic paths including: (i) the mixing of conventionally liquid-phase exfoliated bP (in dimethyl sulfoxide, DMSO) with poly(methyl methacrylate) (PMMA) solution; (ii) the direct exfoliation of bP in a polymeric solution; (iii) the in situ radical polymerization after exfoliating bP in the liquid monomer (methyl methacrylate, MMA). This last methodology concerns the preparation of stable suspensions of bPn-MMA by sonication-assisted liquid-phase exfoliation (LPE) of bP in the presence of MMA followed by radical polymerization. The hybrids characteristics have been compared in order to evaluate the bP dispersion and the effectiveness of the bPn interfacial interactions with polymer chains aimed at their long-term environmental stabilization. The passivation of the bPn is particularly effective when the hybrid material is prepared by in situ polymerization. By using this synthetic methodology, the nanoflakes, even if with a gradient of dispersion (size of aggregates), preserve their chemical structure from oxidation (as proved by both Raman and
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.