Evidence map›Paper›PMID 29870252›Full record

ArticleThe Journal of organic chemistry2018

Evidence for a Sigmatropic and an Ionic Pathway in the Winstein Rearrangement.

Amy A Ott, Mary H Packard, Manuel A Ortuño, Alayna Johnson, Victoria P Suding, Christopher J Cramer, Joseph J Topczewski

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Review
  8. Article
  9. Article
  10. On the Winstein rearrangement: equilibrium and mechanism.ARKIVOC : free online journal of organic chemistry
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Amy A OttDepartment of Chemistry , University of Minnesota Twin Cities , Minneapolis , Minnesota 55455 , United States.ORCID 0000-0002-2018-3276
Mary H PackardDepartment of Chemistry , University of Minnesota Twin Cities , Minneapolis , Minnesota 55455 , United States.
Manuel A OrtuñoDepartment of Chemistry , University of Minnesota Twin Cities , Minneapolis , Minnesota 55455 , United States.
Alayna JohnsonDepartment of Chemistry , University of Minnesota Twin Cities , Minneapolis , Minnesota 55455 , United States.
Victoria P SudingDepartment of Chemistry , University of Minnesota Twin Cities , Minneapolis , Minnesota 55455 , United States.
Christopher J CramerDepartment of Chemistry , University of Minnesota Twin Cities , Minneapolis , Minnesota 55455 , United States.ORCID 0000-0001-5048-1859
Joseph J TopczewskiDepartment of Chemistry , University of Minnesota Twin Cities , Minneapolis , Minnesota 55455 , United States.ORCID 0000-0002-9921-5102

Funding

Chiral α,α-Disubstituted Amine Synthesis by Dynamic Kinetic ResolutionR35GM124718 · NIGMS · UNIVERSITY OF MINNESOTA · PI TOPCZEWSKI, JOSEPH JOHN · 2017 to 2020
$1.5M
Upgrade of a 500 MHz NMR Spectrometer for Applications in Biomedical ResearchS10OD011952 · OD · UNIVERSITY OF MINNESOTA · PI HOYE, THOMAS R. · 2012 to 2012
$378k
National Science Foundation CHE-1413862NIGMS NIH HHS R35 GM124718NIH HHS S10 OD011952
6 · The paper itself

Abstract

The spontaneous rearrangement of allylic azides is thought to be a sigmatropic reaction. Presented herein is a detailed investigation into the rearrangement of several allylic azides. A combination of experiments including equilibrium studies, kinetic analysis, density functional theory calculations, and selective

Indexed as

Allyl CompoundsAzidesCatalysisStereoisomerismAllyl CompoundsAzides

Identifiers

PMID29870252
PMCPMC6076873

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.