ArticleACS catalysis2017
Palladium-Catalyzed Cross-Coupling of Monochlorosilanes And Grignard Reagents.
Article in ACS catalysis, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- A DMAP-enabled strategy for C(spNature communications · 2025Article
- Catalytic Reactions Involving the Oxidative Addition of Si─Halogen and Si─Pseudohalogen Bonds as a Key Step.Chemistry, an Asian journal · 2025Review
- Article
- The role of silicon in drug discovery: a review.RSC medicinal chemistry · 2024Review
- Enantioselective and Regiodivergent Synthesis of Propargyl- and Allenylsilanes through Catalytic Propargylic C-H Deprotonation.Angewandte Chemie (International ed. in English) · 2024Article
- Ligand-modulated nickel-catalyzed regioselective silylalkylation of alkenes.Nature communications · 2023Article
- Facile preparation of organosilanes from benzylboronates andChemical science · 2023Article
- Deep Electroreductive Chemistry: Harnessing Carbon- and Silicon-based Reactive Intermediates in Organic Synthesis.ACS catalysis · 2023Article
- Up-Scale Synthesis ofACS omega · 2022Article
- Nickel-Catalyzed, Reductive C(spAngewandte Chemie (International ed. in English) · 2021Article
- An Electroreductive Approach to Radical Silylation via the Activation of Strong Si-Cl Bond.Journal of the American Chemical Society · 2020Article
- Stereoselective Synthesis ofJournal of the American Chemical Society · 2020Article
- Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates.Angewandte Chemie (International ed. in English) · 2020Article
- Synthesis of Unsaturated Silyl HeterocyclesOrganometallics · 2019Article
- Catalyst-controlled regiodivergent ring-opening C(spChemical science · 2019Article
- Cross-Coupling of Heteroatomic Electrophiles.Chemical reviews · 2019Review
- Copper-catalyzed enantioselective 1,2-borylation of 1,3-dienes.Chemical science · 2018Article
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Authors and funding
3 authors.
Funding
Abstract
Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary and secondary alkyl-magnesium halides is now possible. Arylation with sterically demanding aromatic magnesium halides is also enabled. This transformation overcomes the high bond strength of the Si-Cl bond (113 kcal/mol) and is a rare example of a transition-metal catalyzed process involving its activation. Due to the availability of both chlorosilanes and organomagnesium halide reagents, this method allows for the preparation of a wide range of alkyl and aryl silanes.
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Registered trials
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