ArticleAngewandte Chemie (International ed. in English)2018
Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 33 papers.
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Who cites it
33 citing papers in PubMed.
- Synthesis of the Phospha-Wittig Reagent MeChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Bridged Pyrroloindole-CAYC-Gold Complexes: Harnessing Weak Secondary Intramolecular Au···H-C(spAngewandte Chemie (International ed. in English) · 2026Article
- Secondary Phosphines Bearing N-Heterocyclic Imine Groups: Polarity Umpolung of Highly Electron-Rich P-H Bonds.Inorganic chemistry · 2025Article
- Palladium-Catalyzed Monoarylation of Cyclopropylamine.The Journal of organic chemistry · 2025Article
- Harnessing Organopotassium Reagents for Cross-Coupling with YPhos-Pd Catalysts: Opportunities, Applications, and Challenges.Journal of the American Chemical Society · 2025Article
- Isolation of a Cyclic Trinuclear Gold(I) Complex with Metalated Phosphorus Ylides: Synthesis and Structural Properties.Inorganic chemistry · 2024Article
- Formation of exceptional monomeric YPhos-PdClChemical science · 2022Article
- From Stable PH-Ylides to α-Carbanionic Phosphines as Ligands for Zwitterionic Catalysts.Angewandte Chemie (International ed. in English) · 2022Article
- Ylide-Stabilized Phosphenium Cations: Impact of the Substitution Pattern on the Coordination Chemistry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Tris(tetramethylguanidinyl)phosphine: The Simplest Non-ionic Phosphorus Superbase and Strongly Donating Phosphine Ligand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Single-Site and Cooperative Bond Activation Reactions with Ylide-Functionalized Tetrylenes: A Computational Study.European journal of inorganic chemistry · 2021Article
- Halogen-Bridged Methylnaphthyl Palladium Dimers as Versatile Catalyst Precursors in Coupling Reactions.Angewandte Chemie (International ed. in English) · 2021Article
- Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl- and Amino-Substituted Metallated Ylide.ChemistryOpen · 2021Article
- Au⋅⋅⋅H-C Hydrogen Bonds as Design Principle in Gold(I) Catalysis.Angewandte Chemie (International ed. in English) · 2021Article
- Ylide-Substituted Phosphines with a Cyclic Ylide-Backbone: Angle Dependence of the Donor Strength.Organometallics · 2021Article
- Phosphorus-Containing Superbases: Recent Progress in the Chemistry of Electron-Abundant Phosphines and Phosphazenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
- Coupling of Reformatsky Reagents with Aryl Chlorides Enabled by Ylide-Functionalized Phosphine Ligands.Angewandte Chemie (International ed. in English) · 2021Article
- Easy Access to Enantiomerically Pure Heterocyclic Silicon-Chiral Phosphonium Cations and the Matched/Mismatched Case of Dihydrogen Release.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Towards the rational design of ylide-substituted phosphines for gold(i)-catalysis: from inactive to ppm-level catalysis.Chemical science · 2021Article
- Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and COrganometallics · 2020Article
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Authors and funding
6 authors.
Funding
Abstract
Phosphines are important ligands in homogenous catalysis and have been crucial for many advances, such as in cross-coupling, hydrofunctionalization, or hydrogenation reactions. Herein we report the synthesis and application of a novel class of phosphines bearing ylide substituents. These phosphines are easily accessible via different synthetic routes from commercially available starting materials. Owing to the extra donation from the ylide group to the phosphorus center the ligands are unusually electron-rich and can thus function as strong electron donors. The donor capacity surpasses that of commonly used phosphines and carbenes and can easily be tuned by changing the substitution pattern at the ylidic carbon atom. The huge potential of ylide-functionalized phosphines in catalysis is demonstrated by their use in gold catalysis. Excellent performance at low catalyst loadings under mild reaction conditions is thus seen in different types of transformations.
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