Evidence map›Paper›PMID 29847111›Full record

ArticleJournal of the American Chemical Society2018

Activationless Multiple-Site Concerted Proton-Electron Tunneling.

Miriam A Bowring, Liam R Bradshaw, Giovanny A Parada, Timothy P Pollock, Ricardo J Fernández-Terán, Scott S Kolmar, Brandon Q Mercado, Cody W Schlenker, Daniel R Gamelin, James M Mayer

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Photoinduced Electron vs. Concerted Proton Electron Transfer Pathways in SnChemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Miriam A BowringDepartment of Chemistry , Yale University , New Haven , Connecticut 06520 , United States.
Liam R BradshawDepartment of Chemistry , University of Washington , Seattle , Washington 98195 , United States.
Giovanny A ParadaDepartment of Chemistry , Yale University , New Haven , Connecticut 06520 , United States.
Timothy P PollockDepartment of Chemistry , University of Washington , Seattle , Washington 98195 , United States.
Ricardo J Fernández-TeránDepartment of Chemistry, Ångström Laboratory , Uppsala University , Box 523, SE 75120 Uppsala , Sweden.
Scott S KolmarDepartment of Chemistry , Yale University , New Haven , Connecticut 06520 , United States.ORCID 0000-0002-7797-700X
Brandon Q MercadoDepartment of Chemistry , Yale University , New Haven , Connecticut 06520 , United States.
Cody W SchlenkerDepartment of Chemistry , University of Washington , Seattle , Washington 98195 , United States.ORCID 0000-0003-3103-402X
Daniel R GamelinDepartment of Chemistry , University of Washington , Seattle , Washington 98195 , United States.ORCID 0000-0003-2888-9916
James M MayerDepartment of Chemistry , Yale University , New Haven , Connecticut 06520 , United States.ORCID 0000-0002-3943-5250

Funding

UNDERSTANDING METAL MEDIATED C-H AND O-H BOND OXIDATIONSR01GM050422 · NIGMS · YALE UNIVERSITY · PI MAYER, JAMES M · 1995 to 2020
$6.1M
Unimolecular models to probe multiple-site concerted proton electron transferF32GM109637 · NIGMS · YALE UNIVERSITY · PI BOWRING, MIRIAM A · 2014 to 2015
$99k
NIGMS NIH HHS F32 GM109637NIGMS NIH HHS R01 GM050422
6 · The paper itself

Abstract

The transfer of protons and electrons is key to energy conversion and storage, from photosynthesis to fuel cells. Increased understanding and control of these processes are needed. A new anthracene-phenol-pyridine molecular triad was designed to undergo fast photoinduced multiple-site concerted proton-electron transfer (MS-CPET), with the phenol moiety transferring an electron to the photoexcited anthracene and a proton to the pyridine. Fluorescence quenching and transient absorption experiments in solutions and glasses show rapid MS-CPET (3.2 × 10

Indexed as

ElectronsProtonsAnthracenesFluorescenceHydrogen BondingKineticsMolecular StructurePhenolsPyridinesTemperatureUltraviolet RaysAnthracenesPhenolsProtonsPyridines

Identifiers

PMID29847111
PMCPMC6310214

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.