ReviewChemical science2018
Spin states, vibrations and spin relaxation in molecular nanomagnets and spin qubits: a critical perspective.
Review in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 49 papers.
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Who cites it
49 citing papers in PubMed.
- Axially Chiral Bifluorenylidene Radical Anions with Long Spin-Lattice Relaxation Times at Room Temperature in Fluid Solution.Journal of the American Chemical Society · 2026Article
- Investigation of Hyperfine Interactions in Molecular Spin Qubits Constructed from A Nitronyl-Nitroxide Ligand and Transition Metal Ions.Inorganic chemistry · 2026Article
- Bridging Vibrations and Spins: Mode-Resolved Spin-Phonon Coupling Revealed through THz EPR/Magnetic IR Simulation.The journal of physical chemistry. A · 2026Article
- Br-Mediated Spin-State Control in Nickelocene and Cobaltocene.Journal of the American Chemical Society · 2026Article
- Spectroscopic Signatures of Phonon Character in Molecular Electron Spin Relaxation.ACS central science · 2024Article
- Family of Quasi-Isotropic MnInorganic chemistry · 2024Article
- Synergy of Experiment and Broadened Exploration of Ab Initio Calculations for Understanding of Lanthanide-Pentacyanidocobaltate Molecular Nanomagnets and Their Optical Properties.Inorganic chemistry · 2024Article
- Tunable SIM properties in a family of 3D anilato-based lanthanide-MOFs.Inorganic chemistry frontiers · 2024Article
- Unravelling the role of spin-vibrational coupling in designing high-performance pentagonal bipyramidal Dy(iii) single ion magnets.Chemical science · 2024Article
- Nonlinear and Emissive {[MInorganic chemistry · 2024Article
- Accurate and Efficient Spin-Phonon Coupling and Spin Dynamics Calculations for Molecular Solids.Journal of the American Chemical Society · 2023Article
- Theoretical Magnetic Relaxation and Spin-Phonon Coupling Study in a Series of Molecular Engineering Designed Bridged Dysprosocenium Analogues.Inorganic chemistry · 2023Article
- Improving the molecular spin qubit performance in zirconium MOF composites by mechanochemical dilution and fullerene encapsulation.Chemical science · 2023Article
- Spin-phonon coupling and magnetic relaxation in single-molecule magnets.Chemical Society reviews · 2023Review
- Ultrafast Jahn-Teller Photoswitching in Cobalt Single-Ion Magnets.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Distribution of Bipartite and Tripartite Entanglement within a Spin-1/2 Heisenberg Star in a Magnetic Field.Molecules (Basel, Switzerland) · 2023Article
- The critical role of ultra-low-energy vibrations in the relaxation dynamics of molecular qubits.Nature communications · 2023Article
- Back to the future of organolanthanide chemistry.Chemical science · 2023Review
- Data-driven design of molecular nanomagnets.Nature communications · 2022Article
- Single-molecule magnets beyond a single lanthanide ion: the art of coupling.Chemical science · 2022Review
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Very recently the closely related fields of molecular spin qubits, single ion magnets and single atom magnets have been shaken by unexpected results. We have witnessed a jump in the phase memory times of spin qubits from a few microseconds to almost a millisecond in a vanadium complex, magnetic hysteresis up to 60 K in a dysprosium-based magnetic molecule and magnetic memory up to 30 K in a holmium atom deposited on a surface. With single-molecule magnets being more than two decades old, this rapid improvement in the physical properties is surprising and its explanation deserves urgent attention. The general assumption of focusing uniquely on the energy barrier is clearly insufficient to model magnetic relaxation. Other factors, such as vibrations that couple to spin states, need to be taken into account. In fact, this coupling is currently recognised to be the key factor that accounts for the slow relaxation of magnetisation at higher temperatures. Herein we will present a critical perspective of the recent advances in molecular nanomagnetism towards the goal of integrating spin-phonon interactions into the current computational methodologies of spin relaxation. This presentation will be placed in the context of the well-known models developed in solid state physics, which, as we will explain, are severely limited for molecular systems.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.