ArticleNature communications2018
Coherent X-rays reveal the influence of cage effects on ultrafast water dynamics.
Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
What it found
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Who cites it
18 citing papers in PubMed.
- From Hydrogen Bond Disruption to Accelerated Polymerization: Atomic Mechanisms of Microwave-Accelerated C-A-S-H Gel Formation.ACS omega · 2026Article
- Supercritical density fluctuations and structural heterogeneity in supercooled water-glycerol microdroplets.Nature communications · 2024Article
- Direct observation of ultrafast cluster dynamics in supercritical carbon dioxide using X-ray Photon Correlation Spectroscopy.Nature communications · 2024Article
- Theoretical Studies of Anisotropic Melting of Ice Induced by Ultrafast Nonthermal Heating.ACS physical chemistry Au · 2024Article
- A versatile pressure-cell design for studying ultrafast molecular-dynamics in supercritical fluids using coherent multi-pulse x-ray scattering.The Review of scientific instruments · 2024Article
- Lipid vesicle pools studied by passive X-ray microrheology.The European physical journal. E, Soft matter · 2023Article
- Liquid-liquid phase separation in supercooled water from ultrafast heating of low-density amorphous ice.Nature communications · 2023Article
- Comparing Microscopic and Macroscopic Dynamics in a Paradigmatic Model of Glass-Forming Molecular Liquid.International journal of molecular sciences · 2022Article
- A Benchmark Protocol for DFT Approaches and Data-Driven Models for Halide-Water Clusters.Molecules (Basel, Switzerland) · 2022Article
- Article
- Nanosecond X-ray photon correlation spectroscopy using pulse time structure of a storage-ring source.IUCrJ · 2021Article
- Split-pulse X-ray photon correlation spectroscopy with seeded X-rays from X-ray laser to study atomic-level dynamics.Nature communications · 2020Article
- Emergence of anomalous dynamics in soft matter probed at the European XFEL.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- Accurate contrast determination for X-ray speckle visibility spectroscopy.Journal of synchrotron radiation · 2020Article
- Synchrotron Scattering Methods for Nanomaterials and Soft Matter Research.Materials (Basel, Switzerland) · 2020Review
- Structure and Dynamics of Confined Liquids: Challenges and Perspectives for the X-ray Surface Forces Apparatus.Langmuir : the ACS journal of surfaces and colloids · 2019Article
- The physics and chemistry of ice.Philosophical transactions. Series A, Mathematical, physical, and engineering sciences · 2019Article
- Dynamics of soft nanoparticle suspensions at hard X-ray FEL sources below the radiation-damage threshold.IUCrJ · 2018Article
Corrections and comments
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Authors and funding
29 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The dynamics of liquid water feature a variety of time scales, ranging from extremely fast ballistic-like thermal motion, to slower molecular diffusion and hydrogen-bond rearrangements. Here, we utilize coherent X-ray pulses to investigate the sub-100 fs equilibrium dynamics of water from ambient conditions down to supercooled temperatures. This novel approach utilizes the inherent capability of X-ray speckle visibility spectroscopy to measure equilibrium intermolecular dynamics with lengthscale selectivity, by measuring oxygen motion in momentum space. The observed decay of the speckle contrast at the first diffraction peak, which reflects tetrahedral coordination, is attributed to motion on a molecular scale within the first 120 fs. Through comparison with molecular dynamics simulations, we conclude that the slowing down upon cooling from 328 K down to 253 K is not due to simple thermal ballistic-like motion, but that cage effects play an important role even on timescales over 25 fs due to hydrogen-bonding.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.