Evidence map›Paper›PMID 29763560›Full record

ArticleJournal of the American Chemical Society2018

Mechanism of Ti-Catalyzed Oxidative Nitrene Transfer in [2 + 2 + 1] Pyrrole Synthesis from Alkynes and Azobenzene.

Zachary W Davis-Gilbert, Xuelan Wen, Jason D Goodpaster, Ian A Tonks

Open access · greenAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 37 papers.

0numbers the graph read from it
0cells of the map it votes in
37citing papers in PubMed
7.2field-weighted citation impact, top 2% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

37 citing papers in PubMed, 88 citations in OpenAlex.

  1. Catalytic Sulfur-Atom Transfer Enabled by a Bis(disulfide) Titanium Complex.Angewandte Chemie (International ed. in English) · 2026
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  3. 1,2-Dihydropyrimidine synthesisChemical communications (Cambridge, England) · 2025
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  7. Mechanistic study of pyrazole synthesisDalton transactions (Cambridge, England : 2003) · 2024
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  10. Reassessment of NChemical science · 2022
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  14. Selective propargylic C(spChemical science · 2021
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Zachary W Davis-GilbertDepartment of Chemistry , University of Minnesota - Twin Cities , Minneapolis , Minnesota 55455 , United States.
Xuelan WenDepartment of Chemistry , University of Minnesota - Twin Cities , Minneapolis , Minnesota 55455 , United States.
Jason D GoodpasterDepartment of Chemistry , University of Minnesota - Twin Cities , Minneapolis , Minnesota 55455 , United States.ORCID 0000-0001-6461-4501
Ian A TonksDepartment of Chemistry , University of Minnesota - Twin Cities , Minneapolis , Minnesota 55455 , United States.ORCID 0000-0001-8451-8875
University of Minnesota · US

Funding

Ti-Catalyzed Oxidative Amination ReactionsR35GM119457 · NIGMS · UNIVERSITY OF MINNESOTA · PI Ian Albert Tonks · 2016 to 2026
$4.4M
Upgrade of a 500 MHz NMR Spectrometer for Applications in Biomedical ResearchS10OD011952 · OD · UNIVERSITY OF MINNESOTA · PI HOYE, THOMAS R. · 2012 to 2012
$378k
NIGMS NIH HHS R35 GM119457NIH HHS S10 OD011952
6 · The paper itself

Abstract

A combined computational and experimental study on the mechanism of Ti-catalyzed formal [2 + 2 + 1] pyrrole synthesis from alkynes and aryl diazenes is reported. This reaction proceeds through a formally Ti

Indexed as

AlkynesAzo CompoundsCatalysisCyclizationIminesIsomerismKineticsModels, ChemicalMolecular StructureOxidation-ReductionPyrrolesQuantum TheorySolventsTitaniumAlkynesazobenzeneAzo CompoundsIminesPyrrolesSolventsTitanium

Identifiers

PMID29763560
PMCPMC6508086
OpenAlexW2804571367

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.