ArticleJournal of the American Chemical Society2018
Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- A new 1D Mn(II) coordination polymer: Synthesis, crystal structure, hirshfeld surface analysis and molecular docking studies.Heliyon · 2024Article
- Chiral Motifs in Highly Interpenetrated Metal-Organic Frameworks Formed from Achiral Tetrahedral Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Post-synthetic modifications of metal-organic cages.Nature reviews. Chemistry · 2022Review
- "Eggs in egg cartons": co-crystallization to embed molecular cages into crystalline lattices.Chemical science · 2020Article
- Coordinative-to-covalent transformation, isomerization dynamics, and logic gate application of dithienylethene based photochromic cages.Chemical science · 2020Article
- Recent developments in the construction and applications of platinum-based metallacycles and metallacages via coordination.Chemical Society reviews · 2020Article
- Metal-Organic Pt(II) Hexagonal-Prism Macrocycles and Their Photophysical Properties.Inorganic chemistry · 2019Article
- Solvent-assisted coordination driven assembly of a supramolecular architecture featuring two types of connectivity from discrete nanocages.Chemical science · 2019Article
- Soft Materials with Diverse Suprastructures via the Self-Assembly of Metal-Organic Complexes.Accounts of chemical research · 2019Article
- Assembly of Metallacages into Soft Suprastructures with Dimensions of up to Micrometers and the Formation of Composite Materials.Journal of the American Chemical Society · 2018Article
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Authors and funding
9 authors.
Funding
Abstract
Recently, porous framework materials with various network-type structures have been constructed via several different approaches, such as coordination interactions, reversible covalent bonds, and non-covalent interactions. Here, we have combined the concepts of supramolecular coordination complex (SCC) and metal-organic framework to offer a new strategy to construct a diamondoid supramolecular coordination framework (SCF) from an adamantanoid supramolecular coordination cage as the tetrahedral node and a difunctional Pt(II) ligand as the linear linker via stepwise orientation-induced supramolecular coordination. The adamantanoid supramolecular coordination cage has four uncoordinated pyridyl groups, which serve as the four vertexes of the tetrahedral geometry in the diamondoid framework. As a result, this diamondoid SCF exhibits an adamantanoid-to-adamantanoid substructure with two sets of pores, including the interior cavity of the adamantanoid cage and the extended adamantanoid space between the individual cages in the framework. In addition, the shape-controllable and highly ordered self-assembly of nanometer-sized diamondoid SCF is observed as micrometer-sized regular octahedrons by evaporation under heating in DMSO. This study demonstrates the potential application of supramolecular coordination complexes in the precise construction of highly regulated porous framework materials.
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