Evidence map›Paper›PMID 29741904›Full record

ArticleOrganic letters2018

Stereo- and Regiocontrolled Methylboration of Terminal Alkynes.

Oleksandr Zhurakovskyi, Rafael M P Dias, Adam Noble, Varinder K Aggarwal

Abstract read
In one paragraph

Article in Organic letters, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Zirconium-Based Catalysts in Organic Synthesis.Topics in current chemistry (Cham) · 2022
    Review
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Oleksandr ZhurakovskyiSchool of Chemistry , University of Bristol , Cantock's Close , Bristol BS8 1TS , U.K.ORCID 0000-0002-2096-2202
Rafael M P DiasSchool of Chemistry , University of Bristol , Cantock's Close , Bristol BS8 1TS , U.K.ORCID 0000-0002-0780-8382
Adam NobleSchool of Chemistry , University of Bristol , Cantock's Close , Bristol BS8 1TS , U.K.ORCID 0000-0001-9203-7828
Varinder K AggarwalSchool of Chemistry , University of Bristol , Cantock's Close , Bristol BS8 1TS , U.K.ORCID 0000-0003-0344-6430

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A scalable and operationally simple synthesis of trisubstituted alkenyl boronic esters has been achieved using a Zr-catalyzed carboalumination of terminal alkynes followed by in situ transmetalation with i-PrOBpin. The products are formed in good yields and with excellent regioselectivity and perfect stereoselectivity. The new procedure provides a significant improvement over the previously reported syntheses.

Identifiers

PMID29741904
PMCPMC6007961

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.