ArticleJournal of the American Chemical Society2018
Supramolecular Block Copolymers under Thermodynamic Control.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 44 papers.
What it found
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Who cites it
44 citing papers in PubMed.
- Revisiting Vertical Orientation in Block Copolymer Complexes through Controlled Solvent Vapor Annealing.ACS materials Au · 2026Article
- Supramolecular morphological transition driven by nonequilibrium break-and-build self-organisation.Nature communications · 2026Article
- Noncovalent synthesis of higher-order super-heterostructures from structurally distinct molecular π-systems via secondary nucleation.Nature communications · 2026Article
- PhaseTransfer: A transfer learning framework for efficient phase diagram mapping.npj computational materials · 2026Article
- Twisted Host-Guest Systems Exhibit Superamplification of Asymmetry via Coupled Strong Association and Helicity-Driven Cooperativity.Journal of the American Chemical Society · 2025Article
- Emerging flexible heterojunctions: fabrication, properties and optoelectronic applications.Chemical science · 2025Review
- Evolving Data-Driven Strategies for the Characterization of Supramolecular Polymers and Systems.Angewandte Chemie (International ed. in English) · 2025Review
- Tunable Thermally Activated Delayed Fluorescence from Supramolecular Polymers Toward Application in Aqueous Media.Angewandte Chemie (International ed. in English) · 2025Article
- Simultaneous chirality and energy transfer of donor-acceptor chromophores via bio-inspired supramolecular light-harvesting.Nature communications · 2025Article
- Amplification of Asymmetry for Dynamic Helical Polymers through 1:1 Host-Guest Interactions: Theoretical Models for Majority Rule and Sergeants and Soldiers Effects.Journal of the American Chemical Society · 2025Article
- Non-trivial stimuli-responsive collective behaviours emerging from microscopic dynamic complexity in supramolecular polymer systems.Nature communications · 2025Article
- Enhanced Stability and Properties of Benzene-1,3,5-Tricarboxamide Supramolecular Copolymers through Engineered Coupled Equilibria.Angewandte Chemie (International ed. in English) · 2025Article
- Influence of Tacticity on the Self-Assembly of Poly(ethylene glycol)-ACS macro letters · 2025Article
- Harnessing Competitive Interactions to Regulate Supramolecular "Micelle-Droplet-Fiber" Transition and Reversibility in Water.Journal of the American Chemical Society · 2024Article
- Heat-activated growth of metastable and length-defined DNA fibers expands traditional polymer assembly.Nature communications · 2024Article
- Supramolecular copolymerization of hydrophobic and hydrophilic monomers in liquid crystalline media.Chemical science · 2024Article
- Supramolecular alternating copolymers with highly efficient fluorescence resonance energy transfer.Chemical science · 2023Article
- Interplay Between Hydrogen Bonding and Electron Transfer in Mixed Valence Assemblies of Triarylamine Trisamides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Controllable Construction of Amino-Functionalized Dynamic Covalent Porous Polymers for High-Efficiency COMolecules (Basel, Switzerland) · 2022Article
- Bottom-up supramolecular assembly in two dimensions.Chemical science · 2022Review
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Supramolecular block copolymers are becoming attractive materials in nascent optoelectronic and catalytic technologies. However, their dynamic nature precludes the straightforward tuning and analysis of the polymer's structure. Here we report the elucidation on the microstructure of triarylamine triamide-based supramolecular block copolymers through a comprehensive battery of spectroscopic, theoretical, and super-resolution microscopic techniques. Via spectroscopic analysis we demonstrate that the direct mixing of preassembled homopolymers and the copolymerization induced by slow cooling of monomers lead to the formation of the same copolymer's architecture. The small but pronounced deviation of the experimental spectra from the linear combination of the homopolymers' spectra hints at the formation of block copolymers. A mass balance model is introduced to further unravel the microstructure of the copolymers formed, and it confirms that stable multiblock supramolecular copolymers can be accessed from different routes. The multiblock structure of the supramolecular copolymers originates from the fine balance between favorable hydrogen-bonding interactions and a small mismatch penalty between two different monomers. Finally, we visualized the formation of the supramolecular block copolymers by adapting a recently developed super-resolution microscopy technique, interface point accumulation for imaging in nanoscale topography (iPAINT), for visualizing the architectures formed in organic media. Combining multiple techniques was crucial to unveil the microstructure of these complex dynamic supramolecular systems.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.