ArticleChemical science2018
Super electron donors derived from diboron.
Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
21 citing papers in PubMed.
- A Neutral "Masked" Diborene and Its Reactivity Toward Metal-Free Pyridine Homocoupling.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis of Tetrakis(amino)ethylene-Derived Organic Reductants via Thermal Decomposition of Tris(amino)methanes.Organic letters · 2026Article
- Ring Strain-Promoted Activation of Pyridines by a Saturated BSiAngewandte Chemie (International ed. in English) · 2026Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Boryls, their compounds and reactivity: a structure and bonding perspective.Chemical science · 2024Review
- Oxy-Borylenes as Photoreductants: Synthesis and Application in Dehalogenation and Detosylation Reactions.Angewandte Chemie (International ed. in English) · 2022Article
- NHC induced radical formationChemical science · 2022Article
- Reductive site-selective atypicalScience advances · 2022Article
- Formation of a hydride containing amido-zincate using pinacolborane.Dalton transactions (Cambridge, England : 2003) · 2021Article
- Metal-free thermal organocatalytic pinacol coupling of arylaldehydes using an isonicotinate catalyst with bis(pinacolato)diboron.RSC advances · 2021Article
- Late stage C-H functionalizationChemical science · 2020Review
- Diazaphosphinyl radical-catalyzed deoxygenation of α-carboxy ketones: a new protocol for chemo-selective C-O bond scissionChemical science · 2020Article
- Radical C-N Borylation of Aromatic Amines Enabled by a Pyrylium Reagent.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Electron-Rich, Lewis Acidic Diborane Meets N-Heterocyclic Aromatics: Formation and Electron Transfer in Cyclophane Boranes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications.Chemical science · 2020Article
- Visible Light-Induced Borylation of C-O, C-N, and C-X Bonds.Journal of the American Chemical Society · 2020Article
- An umpolung approach to the hydroboration of pyridines: a novel and efficient synthesis ofChemical science · 2019Article
- New avenues for C-B bond formationChemical science · 2019Review
- Transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters.Chemical science · 2019Article
- Transition Metal-Free 1,2-Carboboration of Unactivated Alkenes.Journal of the American Chemical Society · 2018Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Single-electron transfer is an important process in organic chemistry, in which a single-electron reductant (electron donor) acts as a key component. Compared with metal-based electron donors, organic electron donors have some unique advantages, such as tunable reduction ability and mild reaction conditions. The development of novel organic electron donors with good reduction ability together with ease of preparation is in high demand. Based on the pyridine-catalyzed radical borylation reaction developed in our laboratory, we have discovered that, the reaction system consisting of a diboron(4) compound, methoxide and a pyridine derivative could smoothly produce super electron donors
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.