ArticleJournal of molecular modeling2018
Mechanism for the depolymerization of cellulose under alkaline conditions.
Article in Journal of molecular modeling, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
4 citing papers in PubMed.
- Review
- Characterization by Spectroscopic and Microscopic Techniques of Degraded Zinc White Pigment inACS omega · 2025Article
- Textile Recycling: Efficient Polyester Recovery from Polycotton Blends Using the Heated High-Ethanol Alkaline Aqueous Process.Polymers · 2024Article
- Theoretical exploration of the reactivity of cellulose models under non-thermal plasma conditions-mechanistic and NBO studies.Journal of computational chemistry · 2022Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
The mechanism for the hydroxyl-radical-induced depolymerization of cellulose under alkaline conditions in air was investigated using density functional theory at the B3LYP/6-31+G(d,p) level as well as electron transfer theory. The pathway for the depolymerization of cellulose was obtained theoretically and H abstraction from the C(3) atom of the pyran ring during the cleavage of the glucosidic bond was found to be the rate-limiting step due to its high energy barrier (16.81 kcal/mol) and low reaction rate constant (4.623 × 10
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.