ReviewChemical Society reviews2018
Up in the air: oxygen tolerance in controlled/living radical polymerisation.
Review in Chemical Society reviews, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 77 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
77 citing papers in PubMed, 404 citations in OpenAlex.
- Degradation, Osmosis and the Emergence of Basic Functionalities in Abiotic Synthetic Life-like Chemical Systems.Life (Basel, Switzerland) · 2026Article
- Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations.Angewandte Chemie (International ed. in English) · 2026Review
- A robotic approach to polymerisation kinetics: a case study on copolymerisation parameter estimation.Chemical science · 2026Article
- Heterogeneous photocatalyst enables large-scale broadband light-driven atom transfer radical polymerization with high oxygen and inhibitor tolerance.Nature communications · 2026Article
- Controlled Synthesis of Liquid-Crystalline Polymers Under Ambient Conditions by Red-Light-Driven ATRP.Macromolecules · 2026Article
- Gene Delivery Mediated by Backbone-Degradable RAFT Copolymers.Biomacromolecules · 2026Article
- Oxygen-Tolerant Inverse Microemulsion and Miniemulsion PhotoATRP.ACS macro letters · 2026Article
- Automation-Assisted Photoinduced Atom Transfer Radical Polymerization.ACS polymers Au · 2026Article
- Systematic Optimization of Fluorogenic ARGET ATRP toward Rapid and Oxygen-Tolerant Analyte Detection.ACS omega · 2025Article
- Red Light-Driven, Oxygen-Tolerant RAFT Polymerization Enabled by Methylene Blue.Journal of the American Chemical Society · 2025Article
- Article
- Interplay between the Oxygen Reduction Reaction and Atom Transfer Radical Polymerization with Molecular Cu-Based Catalysts in Water.ACS catalysis · 2025Article
- Open-Air Growth of Polymer Brushes by Surface-Initiated PhotoATRP under Red-Light Irradiation.ACS applied materials & interfaces · 2025Article
- RAFT with Light: A User Guide to Using Thiocarbonylthio Compounds in Photopolymerizations.ACS polymers Au · 2025Article
- Dependence of OInorganic chemistry · 2025Article
- Unraveling the Roles of Amines in Atom Transfer Radical Polymerization in the Dark.Journal of the American Chemical Society · 2025Article
- Unlocking Intracellular Protein Delivery by Harnessing Polymersomes Synthesized at Microliter Volumes using Photo-PISA.Advanced materials (Deerfield Beach, Fla.) · 2024Article
- Evaluation of the Role of [{Cu(PMDETA)}ACS omega · 2024Article
- Mapping Biomaterial Complexity by Machine Learning.Tissue engineering. Part A · 2024Review
- Aerobic mechanochemical reversible-deactivation radical polymerization.Nature communications · 2024Article
17 more citing papers are in PubMed but not listed here.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors at 2 institutions in 3 countries.
Funding
Abstract
The requirement for deoxygenation in controlled/living radical polymerisation (CLRP) places significant limitations on its widespread implementation by necessitating the use of large reaction volumes, sealed reaction vessels as well as requiring access to specialised equipment such as a glove box and/or inert gas source. As a result, in recent years there has been intense interest in developing strategies for overcoming the effects of oxygen inhibition in CLRP and therefore remove the necessity for deoxygenation. In this review, we highlight several strategies for achieving oxygen tolerant CLRP including: "polymerising through" oxygen, enzyme mediated deoxygenation and the continuous regeneration of a redox-active catalyst. In order to provide further clarity to the field, we also establish some basic parameters for evaluating the degree of "oxygen tolerance" that can be achieved using a given oxygen scrubbing strategy. Finally, we propose some applications that could most benefit from the implementation of oxygen tolerant CLRP and provide a perspective on the future direction of this field.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.