Evidence map›Paper›PMID 29698563›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2018

C-Functionalized Cationic Diazaoxatriangulenes: Late-Stage Synthesis and Tuning of Physicochemical Properties.

Irene Hernández Delgado, Simon Pascal, Céline Besnard, Silvia Voci, Laurent Bouffier, Neso Sojic, Jérôme Lacour

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Review
  3. Trioxatriangulenium (TOTAChemical science · 2021
    Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Irene Hernández DelgadoDepartment of Organic Chemistry, University of Geneva, quai Ernest Ansermet 30, 1211, Geneva 4, Switzerland.
Simon PascalDepartment of Organic Chemistry, University of Geneva, quai Ernest Ansermet 30, 1211, Geneva 4, Switzerland.
Céline BesnardLaboratory of Crystallography, University of Geneva, quai Ernest Ansermet 24, 1211, Geneva 4, Switzerland.
Silvia VociUniv. Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, 33400, Talence, France.
Laurent BouffierUniv. Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, 33400, Talence, France.
Neso SojicUniv. Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, 33400, Talence, France.
Jérôme LacourDepartment of Organic Chemistry, University of Geneva, quai Ernest Ansermet 30, 1211, Geneva 4, Switzerland.ORCID http://orcid.org/0000-0001-6247-8059

Funding

Centre National de la Recherche ScientifiqueSchweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung 20'172497Université de BordeauxUniversité de Genève
6 · The paper itself

Abstract

A series of nine C-functionalized cationic diazaoxatriangulene (DAOTA) dyes have been successfully synthesized and fully characterized, including X-ray structural analysis of four derivatives. The introduction of electron-withdrawing or -donating functions enables the tuning of both electro- and photochemical properties with, for instance, two consecutive (reversible) reductions or oxidations observed for nitro or amino derivatives, respectively. The substituents also impacted on the optical properties, with absorption maxima varying from λ=528 to 640 nm and fluorescence being shifted from the yellow to the red range, up to λ=656 nm.

Indexed as

dyes/pigmentselectrochemistryfluorescencesubstituent effectssynthesis design

Identifiers

PMID29698563
PMCPMC6099254

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.