ArticleProceedings of the National Academy of Sciences of the United States of America2018
Phase behaviors of deeply supercooled bilayer water unseen in bulk water.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Conductivity hysteresis in MXene driven by structural dynamics of nanoconfined water.Nature communications · 2025Article
- Ferroelectric 2D ice under graphene confinement.Nature communications · 2021Article
- An ultralow-density porous ice with the largest internal cavity identified in the water phase diagram.Proceedings of the National Academy of Sciences of the United States of America · 2019Article
- New insights into decomposition characteristics of nanoscale methane hydrate below the ice point.RSC advances · 2018Article
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Authors and funding
6 authors.
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Abstract
Akin to bulk water, water confined to an isolated nanoslit can show a wealth of new 2D phases of ice and amorphous ice, as well as unusual phase behavior. Indeed, 2D water phases, such as bilayer hexagonal ice and monolayer square ice, have been detected in the laboratory, confirming earlier computational predictions. Herein, we report theoretical evidence of a hitherto unreported state, namely, bilayer very low density amorphous ice (BL-VLDA), as well as evidence of a strong first-order transition between BL-VLDA and the BL amorphous ice (BL-A), and a weak first-order transition between BL-VLDA and the BL very low density liquid (BL-VLDL) water. The diffusivity of BL-VLDA is typically in the range of 10
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