ArticleChemical science2018
First use of a divalent lanthanide for visible-light-promoted photoredox catalysis.
Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- Solution-Phase Electrochemical Characterization of Acyclic Complexes of Divalent Europium.Inorganic chemistry · 2026Article
- Photochemical strategies in divalent samarium catalysis.Beilstein journal of organic chemistry · 2026Review
- Divalent Intermediates in Lanthanide-Based Photocatalysts: Spectroscopic Characterization and Reactivity.Inorganic chemistry · 2025Article
- Photocatalyst for Visible-Light-Driven Sm(II)-Mediated Reductions.Organic letters · 2024Article
- Photodriven Sm(III)-to-Sm(II) Reduction for Catalytic Applications.Journal of the American Chemical Society · 2024Article
- Expanding the Coordination of f-Block Metals with Tris[2-(2-methoxyethoxy)ethyl]amine: From Molecular Complexes to Cage-like Structures.Inorganic chemistry · 2024Article
- Photocatalytic Generation of Divalent Lanthanide Reducing Agents.Journal of the American Chemical Society · 2023Article
- Photocatalytic dechlorination of unactivated chlorocarbons including PVC using organolanthanide complexes.Chemical communications (Cambridge, England) · 2023Article
- Back to the future of organolanthanide chemistry.Chemical science · 2023Review
- Properties of Amine-Containing Ligands That Are Necessary for Visible-Light-Promoted Catalysis with Divalent Europium.Inorganic chemistry · 2022Article
- Controlled monodefluorination and alkylation of C(spChemical science · 2022Article
- Solid-state and solution-phase characterization of SmDalton transactions (Cambridge, England : 2003) · 2022Article
- Versatile Para-Substituted Pyridine Lanthanide Coordination Complexes Allow Late Stage Tailoring of Complex Function.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Rational Design of High-Relaxivity EuChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Highly efficient and air-stable Eu(II)-containing azacryptates ready for organic light-emitting diodes.Nature communications · 2020Article
- Lanthanide Luminescence in Visible-Light-Promoted Photochemical Reactions.Molecules (Basel, Switzerland) · 2020Review
- Luminescent tungsten(vi) complexes as photocatalysts for light-driven C-C and C-B bond formation reactions.Chemical science · 2020Article
- Measurement of the Dissociation of EuInorganic chemistry · 2020Article
- Reactivity control of a photocatalytic system by changing the light intensity.Chemical science · 2019Article
- Screening of ligands for redox-active europium using magnetic resonance imaging.Bioorganic & medicinal chemistry · 2018Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report the first catalytic use of a divalent lanthanide in visible-light-promoted bond-forming reactions. Our new precatalyst uses europium in the +2 oxidation state and is active in the presence of blue light from light-emitting diodes. The use of low-energy visible light reduces the occurrence of potential side reactions that might be induced by higher-energy UV light. The system described here uses zinc metal as a sacrificial reductant and is tolerant to wet, protic solvents. The catalyst can be made
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.