Evidence map›Paper›PMID 29675168›Full record

ArticleChemical science2018

Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis.

Martin Pawliczek, Takuya Hashimoto, Keiji Maruoka

Open access · diamondAbstract read
In one paragraph

Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
2.2field-weighted citation impact, top 12% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 41 citations in OpenAlex.

  1. Review
  2. Asymmetric phase-transfer catalysis.Nature reviews. Chemistry · 2024
    Review
  3. Article
  4. Enantioselective Kinetic Resolution/Desymmetrization ofAdvanced synthesis & catalysis · 2020
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors at 1 institution in 2 countries.

Martin PawliczekDepartment of Chemistry , Graduate School of Science , Kyoto University , Sakyo , Kyoto , 606-8502 , Japan . Email: takuya@kuchem.kyoto-u.ac.jp ; Email: maruoka@kuchem.kyoto-u.ac.jp.
Takuya HashimotoDepartment of Chemistry , Graduate School of Science , Kyoto University , Sakyo , Kyoto , 606-8502 , Japan . Email: takuya@kuchem.kyoto-u.ac.jp ; Email: maruoka@kuchem.kyoto-u.ac.jp.ORCID 0000-0002-6963-4322
Keiji MaruokaDepartment of Chemistry , Graduate School of Science , Kyoto University , Sakyo , Kyoto , 606-8502 , Japan . Email: takuya@kuchem.kyoto-u.ac.jp ; Email: maruoka@kuchem.kyoto-u.ac.jp.ORCID 0000-0002-0044-6411
Kyoto University · JP

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Herein, we report the first alkylative kinetic resolution of vicinal alcohols realized by cooperative use of a chiral quaternary ammonium salt and an achiral borinic acid. In addition, a catalytic regioselective alkylation of a secondary alcohol in the presence of an unprotected primary one is presented, emphasizing the unique selectivity and potential of this ammonium borinate catalysis.

Identifiers

PMID29675168
PMCPMC5885781
OpenAlexW2773921861

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.